chemistry1

48 Synthetic Routes to AliphaticC-Nitro Formals and acetals prepared from the reaction of polynitroaliphatic alcohols with forma ...

Miscellaneous 49 including 2-fluoro-2,2-dinitroethanol, has been given by Adolph and Koppes.^37 Many more examples of the use of ...

50 Synthetic Routes to AliphaticC-Nitro NO 2 NO 2 I I N H H N NO 2 NO 2 N N NO 2 188 C(NO 2 ) 3 N N NO 2 189 C(NO 2 ) 2 K N H N ...

Chemical stability of polynitroaliphatic compounds 51 Bachmann and Biermann^339 reported the synthesis of nitroalkanes from the ...

68 Polynitropolycycloalkanes more of a science than a balancing act. Correlations between structure and properties such as therm ...

52 Synthetic Routes to AliphaticC-Nitro Table 1.11 Reactions of nitroalkanes and polynitroalkanes with mineral acid Nitroalkane ...

Chemical stability of polynitroaliphatic compounds 53 Table 1.12 Reactions of nitroalkanes and polynitroalkanes with alkali base ...

54 Synthetic Routes to AliphaticC-Nitro salts of polynitroalkanes are exceptionally sensitive to mechanical stimuli and explode ...

Cyclobutanes and their derivatives 69 where the two electronegative nitro groups are positionedanti-periplanar to one another. T ...

References 55 References (a) T. Urba ́nski,Chemistry and Technology of Explosives, Vol. 1, Pergamon Press, Oxford (1964); (b) T ...

70 Polynitropolycycloalkanes Archibald and co-workers^5 found that aminocyclobutanes could be oxidized to the cor- responding ni ...

Cubanes 71 in alkaline solution.^5 No reference is made to the attempted oxidative nitration of (24) to 2,2,5,5,8,8,10,10-octani ...

56 Synthetic Routes to AliphaticC-Nitro L. F. Fieser and M. Fieser,Steroids, Reinholds Publishing Corporation, New York., 43–44 ...

72 Polynitropolycycloalkanes 1,4-Dinitrocubane (28) has been synthesized by Eaton and co-workers^6 ,^8 via two routes both start ...

Cubanes 73 respectively. Fractional recrystallization of this isomeric mixture from diethyl ether affords the 1,3,5,7-isomer (35 ...

74 Polynitropolycycloalkanes (2.028 g/cm^3 ) is higher than octanitrocubane, and so this compound, which is easier to synthe- si ...

Homocubanes 75 Marchand and co-workers^20 synthesis of 5,5,9,9-tetranitropentacyclo[5.3.0.0^2 ,^6 .0^3 ,^10 .0^4 ,^8 ] decane (5 ...

76 Polynitropolycycloalkanes Tests onD 3 -hexanitrotrishomocubane show it to be both less sensitive and significantly more power ...

Homocubanes 77 gem-dinitro group via the oxime (67). Deprotection of the acetal (70), followed by elaboration of the ketone func ...

78 Polynitropolycycloalkanes OH OH OH OH Br Br Br Br O O Br Br O O O O Br Br Br Br O OO O Br Br HOOC COOH COOH HOOC ClOC COCl Cl ...