chemistry1

Halide displacement 7 treatment of the resultingβ-nitroalkyl bromide with triethylamine, is also a general route to α-nitroalken ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Organic Chemistry of Explosives Dr. Jai Prakash Agrawal CChem FRSC (UK) Former D ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 iii ...

8 Synthetic Routes to AliphaticC-Nitro XCH 2 (CH 2 )nCH 2 XO 2 NCH 2 (CH 2 )nCH 2 NO 2 NaNO 2 , DMF phloroglucinol, (NH 2 ) 2 CO ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Organic Chemistry of Explosives i ...

Halide displacement 9 1.5.2 Modified Victor Meyer reaction The synthesis of aliphatic nitro compounds from the reaction of alkyl ...

10 Synthetic Routes to AliphaticC-Nitro CH 3 CH 2 CH 2 CH 2 SO 2 CH 3 CH 3 CHBrCO 2 Et Br DMF DMF DMF DMSO DMF DMF H 3 CCH 2 CH ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 ii ...

Halide displacement 11 in alkaline solution. These reactions are believed^100 to go via the tautomericα-halonitronic acid (12) r ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Organic Chemistry of Explosives Dr. Jai Prakash Agrawal CChem FRSC (UK) Former D ...

12 Synthetic Routes to AliphaticC-Nitro in aqueous potassium carbonate forms the potassium salt of 1,1-dinitroethane (24), which ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Copyright©C 2007 John Wiley & Sons Ltd, The Atrium, Southern Gate, Chicheste ...

Halide displacement 13 1.5.4 Displacements using nitronate salts as nucleophiles Nitronate salts can react with alkyl halides to ...

Contents Foreword pagexi Preface xiii Abbreviations xv Acknowledgements xxiii ...

14 Synthetic Routes to AliphaticC-Nitro The reactions of alkyl halides with the silver salt of dinitroacetonitrile have been sho ...

...

Oxidation and nitration of C N bonds 15 available ketone groups to nitro andgem-dinitroaliphatic functionality is usually via th ...

Contents vii ...

16 Synthetic Routes to AliphaticC-Nitro Yields are frequently moderate for Scholl reactions. Aldoximes are not usually compatibl ...

...