chemistry1

Oxidation and nitration of C N bonds 17 Dinitrogen pentoxide has also been used to synthesize aryldinitromethanes from arylal- d ...

- JWBK121-FM October 11, 2006 21:10 Char Count= 1 Synthetic Routes to AliphaticC-Nitro Functionality Background xxv 1.1 In ...

18 Synthetic Routes to AliphaticC-Nitro NOH HON NOH NO 2 NO 2 NO 2 NO 2 O 2 N O 2 N O 2 N NOH HON H H NOHHON H H (CF 3 CO) 2 O, ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 x Contents 9.10 SelectiveO-nitration 361 9.10.1 Glycidyl nitrate and NIMMO – bat ...

Oxidation and nitration of C N bonds 19 1.6.1.4 Halogenation–oxidation–reduction route C NOH R R R 2 C Br NO R 2 C Br NO 2 R 2 C ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Foreword In the past a significant amount of research worldwide was directed at ...

20 Synthetic Routes to AliphaticC-Nitro HON NOH NOH NOH NO 2 NO 2 NO 2 NO 2 NO 2 NO 2 NO 2 H H O 2 N O 2 N O 2 N H H NOH NOH H H ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xii ...

Oxidation and nitration of C N bonds 21 NH 2 NH 2 NH 2 NH 2 NH 2 H H H H H 2 N NO 2 NO 2 NO 2 NO 2 NO 2 NO 2 NO 2 O 2 N O 2 N O ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Preface Explosives have attracted a lot of unwanted publicity over the years for ...

22 Synthetic Routes to AliphaticC-Nitro C HNO 2 K C 2 N NOHO X X C(NO 2 ) 3 X X = m-NO 2 , 60 % X = p-NO 2 , 58 % X = H, 77 % X ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xiv Preface nitration to the synthesis of modern high performance explosives via ...

Oxidation and nitration of C N bonds 23 1.6.4 Oxidation of pseudonitroles KOH (aq) (CH 3 ) 2 CHNO 2 CH 3 C CH 3 NO 2 K (CH 3 ) 2 ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Abbreviations Ac Acetyl [CH 3 CO] ADN Ammonium dinitramide ADNBF 7-Amino-4,6-din ...

24 Synthetic Routes to AliphaticC-Nitro (69) is formed in 85 % yield via the oxidation of the corresponding bis-isocyanate (81) ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xvi Abbreviations i-Bu iso-Butyl [(CH 3 ) 2 CHCH 2 ] n-Bu normal-Butyl [CH 3 (CH ...

Kaplan–Shechter reaction 25 A range of primary and secondary nitroalkanes and their derivatives have been converted to the corre ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Abbreviations xvii DMF Dimethylformamide DMSO Dimethylsulfoxide DNABF 4,4′-Dinit ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xviii Abbreviations HMX 1,3,5,7-Tetranitro-1,3,5,7-tetraazacyclooctane HNAB 2,2′ ...

26 Synthetic Routes to AliphaticC-Nitro Homologue n = 1 2 3 4 5 0 0 10 84 89 0 49 25 70 --- via the dinitroalkane (83) via the b ...