chemistry1

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Abbreviations xix NIMMO 3-Nitratomethyl-3-methyloxetane NMHP 5-(Nitratomethyl)-1 ...

Nitration of compounds containing acidic hydrogen 27 ferricyanide oxidant in the presence of sodium nitrite. The process was lat ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xx Abbreviations SDATO 1,3-Bis(1,2,4-triazol-3-amino)-2,4,6-trinitrobenzene (BTA ...

28 Synthetic Routes to AliphaticC-Nitro Feuer and co-workers^209 conducted extensive studies into alkaline nitration with nitrat ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Abbreviations xxi Ts Tosyl or 4-toluenesulphonyl [4-MeC 6 H 4 SO 2 ] UDMH Unsymm ...

Nitration of compounds containing acidic hydrogen 29 NCCH 2 (CH 2 ) 2 CH 2 CN O 2 NCH 2 (CH 2 ) 2 CH 2 NO 2 CCH 2 CH 2 C NO 2 CN ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxii ...

30 Synthetic Routes to AliphaticC-Nitro carbanions such as malonate arises from the perturbation of a side-reaction observed wit ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Acknowledgements While writing this book we have consulted innumerable research ...

Nitration of compounds containing acidic hydrogen 31 inductive effect of three nitro groups and the increased sp^2 character of ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxiv Acknowledgements R. G. Coombes, “Nitro and Nitroso Compounds,” inComprehen ...

32 Synthetic Routes to AliphaticC-Nitro Trinitroacetonitrile (110), a precursor to dinitroacetonitrile and its derivatives, can ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Background In the simplest terms, an explosive is defined as a substance, which ...

Addition and condensation reactions 33 1.10 ADDITION AND CONDENSATION REACTIONS Primary and secondary nitroalkanes, and substrat ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxvi Background primary explosives are poor initiators while others are powerful ...

34 Synthetic Routes to AliphaticC-Nitro the reaction of nitroform (112) with the corresponding vinyl ethers.^243 The synthesis o ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 Background xxvii Most organic explosives contain nitrate ester, nitramine, or al ...

Addition and condensation reactions 35 HC COEt NO 2 NO 2 119 Hg(OAc) 2 H 3 C OEt OCH 2 CF(NO 2 ) 2 OCH 2 CF(NO 2 ) 2 126 125 CH ...

JWBK121-FM October 11, 2006 21:10 Char Count= 0 xxviii ...

36 Synthetic Routes to AliphaticC-Nitro H 2 C CHCO 2 Me NO 2 NO 2 127 O 2 N NO 2 NO 2 128 O 2 N HC(NO 2 ) 3 + Steps C CH 2 CH 2 ...