chemistry1

Halide displacement 9 1.5.2 Modified Victor Meyer reaction The synthesis of aliphatic nitro compounds from the reaction of alkyl ...

Derivatives of polynitroaliphatic alcohols 47 in the presence of TFAA or PPA as condensing agents;^310 ,^313 ,^314 (4)trans-este ...

48 Synthetic Routes to AliphaticC-Nitro Formals and acetals prepared from the reaction of polynitroaliphatic alcohols with forma ...

10 Synthetic Routes to AliphaticC-Nitro CH 3 CH 2 CH 2 CH 2 SO 2 CH 3 CH 3 CHBrCO 2 Et Br DMF DMF DMF DMSO DMF DMF H 3 CCH 2 CH ...

Miscellaneous 49 including 2-fluoro-2,2-dinitroethanol, has been given by Adolph and Koppes.^37 Many more examples of the use of ...

Halide displacement 11 in alkaline solution. These reactions are believed^100 to go via the tautomericα-halonitronic acid (12) r ...

12 Synthetic Routes to AliphaticC-Nitro in aqueous potassium carbonate forms the potassium salt of 1,1-dinitroethane (24), which ...

50 Synthetic Routes to AliphaticC-Nitro NO 2 NO 2 I I N H H N NO 2 NO 2 N N NO 2 188 C(NO 2 ) 3 N N NO 2 189 C(NO 2 ) 2 K N H N ...

Halide displacement 13 1.5.4 Displacements using nitronate salts as nucleophiles Nitronate salts can react with alkyl halides to ...

Chemical stability of polynitroaliphatic compounds 51 Bachmann and Biermann^339 reported the synthesis of nitroalkanes from the ...

52 Synthetic Routes to AliphaticC-Nitro Table 1.11 Reactions of nitroalkanes and polynitroalkanes with mineral acid Nitroalkane ...

Chemical stability of polynitroaliphatic compounds 53 Table 1.12 Reactions of nitroalkanes and polynitroalkanes with alkali base ...

14 Synthetic Routes to AliphaticC-Nitro The reactions of alkyl halides with the silver salt of dinitroacetonitrile have been sho ...

54 Synthetic Routes to AliphaticC-Nitro salts of polynitroalkanes are exceptionally sensitive to mechanical stimuli and explode ...

Oxidation and nitration of C N bonds 15 available ketone groups to nitro andgem-dinitroaliphatic functionality is usually via th ...

References 55 References (a) T. Urba ́nski,Chemistry and Technology of Explosives, Vol. 1, Pergamon Press, Oxford (1964); (b) T ...

16 Synthetic Routes to AliphaticC-Nitro Yields are frequently moderate for Scholl reactions. Aldoximes are not usually compatibl ...

56 Synthetic Routes to AliphaticC-Nitro L. F. Fieser and M. Fieser,Steroids, Reinholds Publishing Corporation, New York., 43–44 ...

Oxidation and nitration of C N bonds 17 Dinitrogen pentoxide has also been used to synthesize aryldinitromethanes from arylal- d ...

References 57 J. M. Birchall, A. J. Bloom, R. N. Haszeldine and C. J. Willis,J. Chem. Soc., 1962, 3021. (a) H. Petri,Z. Anorg. ...