parameters by fitting the model to experimental data on substrate consumption rates in
laboratory or larger scale reactors. Most of the time, the external mass transfer resistances
were not taken into account, and only the apparent kinetic constants were estimated.
Since it is considered that in wastewater treatment processes using biofilms the apparent
kinetic order is in most cases 1/2 (Harremöes, 1978), Table 10.2 indicates typical values
of the apparent half order constant (k1/2ap), which, from Equation (27), is:
(^) (43)
Although the data in Table 10.2 display some scattering, the order of magnitude of the
k1/2ap values is the same and there are no large inconsistencies in aerobic heterotrophic
and autotrophic systems. This is somehow remarkable in view of the considerable
differences between the cases studied (different reactors, different substrates, etc.), often
without a real accurate control of the measured variables. Anyhow, design
Table 10.2 Apparent half order kinetic constants in
wastewater treatment (k1/2ap.)
Biological process and
Limiting metabolic factor
Reactor type K1/2ap·10^5
(kg1/2.m−1/2.s−^1 )
Reference
Aerobic, heterotrophic biomass
Oxygen
Fixed bed 0.12 Grasmick et al.
(1982)
Aerobic, heterotrophic biomass
Oxygen
Rotating drum 0.12–0.15 Harremöes et al.
(1980)
Aerobic, heterotrophic biomass
Glucose
Rotating drum 0.12 Harremöes (1978)
Harremöes et al.
(1980)
Aerobic, heterotrophic biomass
Toluene
Waste gas
trickling filter
0.07–0.11 Pederson and Arvin
(1996)
Nitrification, autotrophic biomass
Oxygen
Rotating disk 0.075–0.14 Gönenç and
Harremöes (1985)
Nitrification, autotrophic biomass
Oxygen
Submerged filter 0.05–0.10 Çeçen and Gönenç
(1994)
Nitrification, autotrophic biomass
Oxygen
Circulating bed
reactor
0.15 Nogueira et al.
(1998)
Nitrification, autotrophic biomass
Ammonium
Rotating disk 0.06 Gönenç and
Harremöes (1985)
Anaerobic, methanogenic
biomass Acetate
Downflow filter 0.12 Hamoda and
Kennedy (1987)
Anaerobic, methanogenic
biomass Acetate
UASB 0.05 Brito and Melo
(1997)
Anaerobic, methanogenic
biomass Molasses
Upflow filter 0.04–0.48 Gönenç et al. (1991)
Biofilm reactors 313