1549380323-Statistical Mechanics Theory and Molecular Simulation

(jair2018) #1
The ideal boson gas 439

〈f 0 m〉=

〈N〉


g

. (11.6.35)


Summing both sides of eqn. (11.6.35) overmcancels the degeneracy factorgon the
right, yielding



m

〈f 0 m〉=


m

〈N〉


g

〈f ̄ 0 〉=〈N〉, (11.6.36)

where〈f ̄ 0 〉indicates that the spin degeneracy has been summed over. ForT > T 0 ,
ρλ^3 /g < R(3/2) andζis not within 1/Vof 1, implying thatζ/(1−ζ) is finite and


〈f ̄ 0 〉
〈N〉

=


1


〈N〉


ζ
1 −ζ

−→ 0 (11.6.37)


as〈N〉→∞. Thus, for the occupation of the ground state, we obtain


〈f ̄ 0 〉
〈N〉

=





1 −(T/T 0 )^3 /^2 T < T 0


0 T > T 0


. (11.6.38)


A plot of eqn. (11.6.38) is given in Fig. 11.4.


0 1


T/T 0


0


1


<f

>/< 0


N


>


Fig. 11.4Plot of eqn. (11.6.38).
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