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ACKNOWLEDGMENTS
The manuscript was improved by the insightful reviews of
anonymous reviewers. We thank Y. Yang (University of California,
Los Angeles), Y. Li (Beijing Institute of Technology), H. Xie (Central
South University), Q. Bao (East China Normal University), and

J. Xiao (Beijing Institute of Technology) for insightful data analysis
and valuable discussion. We also thank the third certification
institutions National Institute of Metrology (China) and Newport
Technology and Application Center PV Lab (USA) for
authentication tests; beamline BL14B1 (Shanghai Synchrotron
Radiation Facility, SSRF) for providing beam time and help during
the experiments; and Enli technology Co., Ltd. for help with PV
efficiency and EQE measurement.Funding:This work was
supported by National Natural Science Foundation of China
(nos. 91733301, 51672008, 51722201, 21425101, 21331001, and
21621061), MOST of China (2014CB643800), National Key
Research and Development Program of China (grant nos.
2017YFA0206701 and 2017YFA0205101), Beijing Natural Science
Foundation (4182026), National Key Research and Development
Program of China (grant no. 2016YFB0700700), National
Natural Science Foundation of China (51673025), Beijing Municipal
Science and Technology Project (no. Z181100005118002), and
Young Talent Thousand Program.Author contributions:L.W. and
H.Z. conceived the idea and designed the project. H.Z., C.-H.Y.,
and L.-D.S. directed and supervised the research. L.W. fabricated
and characterized devices. Y.H., Y.C., L.L., Z.X., and N.L. also
contributed to device fabrication. L.W. performed the SEM, PL,
UPS, UV-vis, XPS, and XRD measurements. GIWAXS was
performed and analyzed by G.Z., supported by BL14B1 beamline of
SSRF. B.D. and Z.L. performed EPR. M.S. and B.H. carried out DFT
calculation. L.W. drafted the manuscript; Q.C. and H.Z. revised and
finalized the manuscript.Competing interests:The authors have no
competing interests.Data and materials availability:All data are
available in the main text or the supplementary materials.

SUPPLEMENTARY MATERIALS
http://www.sciencemag.org/content/363/6424/265/suppl/DC1
Materials and Methods
Supplementary Text
Figs. S1 to S18
Tables S1 to S3
References ( 52 – 57 )
24 June 2018; resubmitted 25 September 2018
Accepted 28 November 2018
10.1126/science.aau5701

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