(^2) ( 1)
( )
2
Mv
T K K Kelvin
R
6.Sol: Number of moles of first gas
1
A
n
N
Number of of moles of second gas
2
A
n
N
Number of of moles of third gas
3
A
n
N
By conserving total internal energy
UfUi
1 2 3
1 2 3
A A A
n RT n RT n RT
N N N
^123 mix
A
n n n RT
N
1 1 2 2 3 3
1 2 3
mix
T n T n T n T
n n n
7.Sol:
.^55
2 2
K E nRT PV
5 5 1 8 10^44
5 10
2 2 4
mP m
J V
d d
8.Sol: The speed of sound in a gas is given by
v RT
M
2 2
2
O O He
He O He
v M
v M
1.4 (^4) 0.3237
32 1.67
(^2460) 1421 /
0.3237 0.3237
O
He
v
v m s
9.Sol: Molar specific heat '
Q
C
n T
Specific heat
C Q
m T
'
C m M(Molecular weight)
C n
'
C
C
M
' 1
CP CV R
MCP MCV R P V
C C R
M
For nitrogen M= 28
28
CP CV R
CALORIMETRY [ONLINE QUESTIONS]
1.Sol: According to principle of calorimetry,
QgivenQused
0.2 s 150 40
0.15 1 40 25 0.025 40 25
0.175(15)
0.1193 499.46
0.2 110
cal J
s
g C kg C
2.Sol: As Pt mc T
P 10 60 mc 1 100
(i) and P 55 60 mL
(ii) Dividing equation (i) by (ii) we get
10 100
55 L
L 550. / .cal g
3.Sol: Energy given by heater must be equal to
the sum of energy gained by water and energy
lost from the lid.
Pt ms T energy lost
1000 t 2 4.2 10^3 50 160t
840 8.4 10 50t ^3
t = 500 s = 8 min 20 s.
4.Sol: As the surrounding is identical, vessel is
identical time taken to cool both water and
liquid (from 30 to 25 C C) is same 2 minutes,
therefore
6.Sol:
7.Sol:
8.Sol:
9.Sol:
CALORIMETRY[ONLINE QUESTIONS]
1.Sol:
2.Sol:
3.Sol:
4.Sol:
water liquid
dQ dQ
dt dt
(m cw w W T) (m cl l W T)
t t
(W= water equivalent of the vessel)
or, m cw wm cl l
Specific heat of liquid,
W W
l
l
c m c
m
50 1 0.5 /
100
kcal kg