76 CHAPTER5. DYNAMICSOFTHEQUANTUMSTATE
5.6 Group Velocity and Phase Velocity
We have seen that the expectation value of position< x > moves at avelocity
v=
/m. ThisisaconsequenceofEhrenfest’sprincipleforafreeparticle. On
theotherhand,thevelocityvphaseofanyplanewaveisgivenbytheusualformula
vphase=λf (5.87)
sothatforaDeBrogliewaveofadefinitemomentump
vphase =
h
p
Ep
h
=
Ep
p
=
p^2 / 2 m
p
=
p
2 m
(5.88)
whichishalfthevelocitythatonemightexpect,sinceaclassicalparticlewithmo-
mentumpmovesatavelocityp/m.Thereisnocontradiction,however. Thevelocity
vphase=λfofaplanewaveisknownasthe”phasevelocity”ofthewave;itrefers
tothespeedatwhichapointofgivenphaseonthewave(acrestoratrough,say),
propagatesthroughspace. However,thatisnotnecessarilythesamespeedatwhich
theenergycarriedbyagroupofwavestravelsthroughspace.Thatvelocityisknown
asthe”groupvelocity”.
Considerawavewhichisasuperpositionoftwoplanewavesoffrequenciesf 1 ,f 2 ,
andwavelengthsλ 1 ,λ 2 ,respectively,andwhichhavethesameamplitudeA. Wewill
assumethatthedifferencebetweenfrequencies∆fismuchsmallerthantheaverage
frequencyf,i.e.
∆f<<f and ∆λ<<λ (5.89)
Bythesuperpositionprincipleofwavemotion
ψ(x,t) = ψ 1 (x,t)+ψ 2 (x,t)
= A
[
ei(k^1 x−ω^1 t)+ei(k^2 x−ω^2 t)
]
= 2 Aei(kx−ωt)cos[
1
2
i(∆kx−∆ωt)] (5.90)
whichistheproductoftwowaves,oneofwhichismovingwiththevelocity
vphase=
ω
k
(5.91)
andtheothermovingwithvelocity
vgroup=
∆ω
∆k