7.3. EIGENSTATESASSTATESOFZEROUNCERTAINTY 107
Ameasurementprocessthereforehasthepropertythat,whateverthephysicalstate
oftheobjectmaybeatthetimejustpriortothemeasurement,thesystemisleftin
oneoftheeigenstatesofO ̃atatimejustafterthemeasurement.
Wecangofurther.Giventhattheexpectationvalueoftheobservable
theeigenstateφistheeigenvalueλ,andgiventhattheuncertainty∆O= 0 vanishes,
itfollowsthatameasurementofOcouldonlyresultinthevalueO=
Anymeasurementthat wasdifferentfromthemeanvaluewould implyanon-zero
uncertainty. Butsincetheresultofameasurementistoleavethesysteminsucha
zero-uncertaintystate,itfollowsthat
II)AmeasurementoftheobservableOcanonlyresultinavaluewhichis
equaltooneoftheeigenvaluesofthecorrespondingoperatorO ̃.
Ingeneraltherearemanysolutionsφ(x),λtotheeigenvalueequation(7.53),soit
isusefultodenoteasetoflinearlyindependentsolutionsas{φα(x),λα},withdifferent
solutionsdistinguishedbythevalueofthesubscriptα. Theeigenvalueequationis
written
O ̃φα=λαφα (7.54)
withφαtheeigenstateandλα thecorresponding eigenvalue. Ifalltheeigenvalues
aredifferent,theeigenvaluesaresaidtobenon-degenerate. Iftherearenlinearly-
independenteigenstatesφα 1 ,φα 2 ,...,φαnwhoseeigenvaluesarethesame,i.e. λα 1 =
λα 2 =...=λαn,thentheeigenvalueissaidtoben-folddegenerate. Forexample,
theenergyeigenvaluesof afreeparticlearetwo-folddegenergate,becauseforeach
eigenvalueEtherearetwolinearlyindependenteigenstates,e.g.
ei
√ 2 mE/ ̄h
and e−i
√ 2 mE/ ̄h
(7.55)
whichsatisfy
H ̃φ=− ̄h
2
2 m
∂^2
∂x^2
φ=Eφ (7.56)
TheoremH1
TheeigenvaluesofanHermitianoperatorarereal.
Proof:ThisfollowsdirectlyfromthedefinitionofanHermitianoperator
<ψ|O|ψ> isreal (7.57)
Chooseψtobeaneigenstateφα
<φα|O|φα>=λa<φα|φα> (7.58)
Sincetheinnerproductofanyvectorwithitselfisarealnumber,itfollowsthatthe
lhsisrealifandonlyifλαisreal.