QMGreensite_merged

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21.3. HILBERTSPACE 333


Writtenoutas∞×∞matrices,XandPare

X = L








1
2 −

16
9 π^20...
− 916 π 2 12 − 2548 π 2...
0 − 2548 π 2 12...

......
......
......








P =


ih ̄
L







0 83 0...


−^830245...


0 −^2450...


......


......


......








(21.184)


whicharebothclearlyHermitian.


Exercise: Calculatethe 11 matrixelementofthe[X,P]commutatorapproximately,
inthesquarewellrepresentation,using


[X,P]mn=

∑∞

k=1

[XmkPkn−PmkXkn] (21.185)

Carryoutthesumoverktok=16.



  • TheAngularMomentumRepresentation


Asafinalexample,weconsidertheHilbertspacespannedbytheeigenstatesof
angularmomentum


J^2 |jm> = j(j+1) ̄h^2 |jm>
Jz|jm> = m ̄h|jm> (21.186)

Inthespecialcasethatjisaninteger,theinnerproductof|jm>witheigenstates
ofangles|θ,φ>givesthesphericalharmonics


Yjm(θ,φ)=<θφ|jm> (21.187)

Thesphericalharmonicsarethewavefunctionsofeigenstatesofangularmomentumin
the”anglebasis,”spannedbythetheset{|θ,φ>}ofangleeigenstates(arigidrotator
inan angleeigenstates has adefinite angular positionθ,φ However, the angular
momentumalgebra alsoallows forhalf-integer eigenvalues j = 1 / 2 , 3 / 2 , .... In
particular,thej= 1 / 2 caseisimportantfordescribingthespinangularmomentum

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