Cracking the SAT Chemistry Subject Test

(Marvins-Underground-K-12) #1

  1. A Lewis acids are molecules/ions that can accept a pair of nonbonding
    electrons to form a covalent bond. Not surprisingly, molecules/ions that
    contain an atom with an incomplete octet are good Lewis acids. The only
    choice that has an atom without a stable octet (or bitet in the case of H) is
    the carbon in choice (A).

  2. D According to the reaction, 6 Ca atoms are present in the reactants.
    Therefore, 6 CaSiO 3 must be present as products, choice (D).

  3. B Percent by mass is calculated by dividing the mass of the solute by the
    total mass of the solution. 40.0 mL of water would have a mass of 40.0 g
    (density of water = 1.0 g/mL), so the total mass of the solution would be
    10.0 g + 40.0 g = 50.0 g. Then, (10.0 g/50.0 g) × 100% = 20%

  4. E Given that the molecular weight of AgCl is 143.4 g/mol, the number of
    moles of AgCl precipitated is


Moles   AgCl    =   5.70    g/143.4 g/mol

                                                                                    =   0.040   moles

Since   the molar   ratio   of  Ag+ in  AgCl    is  1,  the number  of
moles of Ag+ in the original solution was also 0.040.
Therefore, the concentration of the original solution was

Molarity    Ag+ =   moles   Ag+/volume  (L)

                                                                                            =   0.040   moles/0.100 L

                                                                                            =   0.40    M   (choice E)


  1. A Choices (B), (C), (D), and (E) are all true statements. Choice (A) is a
    false statement—the vapor pressure of a substance depends only upon 1)
    the substance’s temperature and 2) its mole fraction when it’s in solution
    (see the colligative property of vapor pressure depression).

  2. B This is a bit of a trick question; when using any gas law that involves
    temperature the Kelvin scale must be used. However, Boyle’s Law (P 2 V 2
    = P 2 V 2 ) is only used when temperature is held constant, and thus, the

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