5.1 CHAPTER 5. THE PERIODIC TABLE
Element^2311 Na^2412 Mg^2713 Al^2814 Si^3115 P^3216 S^3517 Cl
Chlorides NaCl MgCl 2 AlCl 3 SiCl 4 PCl 5 or
PCl 3
S 2 Cl 2 no chlo-
rides
Oxides Na 2 O MgO Al 2 O 3 SiO 2 P 4 O 6 or
P 4 O 10
SO 3 or
SO 4
Cl 2 O 7 or
Cl 2 O
Valence elec-
trons
3 s^13 s^23 s^23 p^13 s^23 p^23 s^23 p^33 s^23 p^43 s^23 p^5
Atomic
radius
Decreases across a period.
First Ioniza-
tion energy
The general trend is an increase across the period.
Electro-
negativity
Increases across the period.
Melting and
boiling point
Increases to silicon and then decreases to argon.
Electrical
conductivity
Increases from sodium to aluminium. Silicon is a semi-conductor.
The rest are insulators.
Table 5.1: Summary of the trends in period 3
Note that we have left argon (^4018 Ar) out. Argon is a noble gas with electron configuration:
[Ne] 3 s^23 p^6. Argon does not form any compounds with oxygen or chlorine.
Exercise 5 - 1
1. Use Table 5.1 and Figure 5.2 to help you produce a similar table for the
elements in period 2.
2. Refer to the data table below which gives the ionisation energy (in kJ·
mol−^1 ) and atomic number (Z) for a number of elements in the periodic
table:
98 Chemistry: Matter and materials