CHAPTER 3. STATES OF MATTER AND THE KINETIC MOLECULAR THEORY 3.2
The kinetic molecular
theory
ESAAL
Thekinetic theory of matterhelps us to explain why matter exists in differentphases(i.e.
solid, liquid and gas), and how matter can change from one phase to the next. The kinetic
theory of matter also helps us to understand other properties of matter. It is important to
realise that what we will go on to describe is only atheory. It cannot be proved beyond
doubt, but the fact that it helps us to explain our observations of changes in phase, and
other properties of matter, suggests that it probably is more than just a theory.
Broadly, the kinetic theory of matter says that all matter is composed ofparticleswhich
have a certain amount ofenergywhich allows them to move at different speeds depending
on the temperature (energy). There arespacesbetween the particles and alsoattractive
forcesbetween particles when they come close together.
solid liquid gas
Figure 3.4: The three states of matter
Table 3.2 summarises the characteristics of the particles that are in each phase of matter.
Taking copper as an example we find that in the solid phase the copper atoms have little
energy. They vibrate in fixed positions. The atoms are held closely together in a regular
pattern called alattice. If the copper is heated, the energy of the atoms increases. This
means that some of the copper atoms are able to overcome the forces that are holding
them together, and they move away from each other to formliquid copper. This is why
liquid copper is able to flow, because the atoms are more free to move than when they
were in the solid lattice. If the liquid is heated further, it will become a gas. Gas particles
have lots of energy and are far away from each other. That is why it is difficult to keep a
gas in a specific area! The attractive forces between the particles are very weak. Gas atoms
will fill the container they are in. Figure 3.1 shows the changes in phase that may occur in
matter, and the names that describe these processes.
Activity: The three phases of water
Chemistry: Matter and Materials 59