Encyclopedia of the Solar System 2nd ed

(Marvins-Underground-K-12) #1
The Moon 243

TABLE 2 Elemental Abundancesa

Oxide (weight Cl Earth Mantle Bulk Highlands Low-Ti High-Ti
percent) +Crust Moon Basalt Basalt

SiO 2 34.2 49.9 47 45.0 43.6 37.8
TiO 2 0.11 0.16 0.3 0.56 2.60 13.0
Al 2 O 3 2.44 3.64 6.0 24.6 7.87 8.85
FeO 35.8 8.0 13.0 6.6 21.7 19.7
MgO 23.7 35.1 29 6.8 14.9 8.44
CaO 1.89 2.89 4.5 15.8 8.26 10.7
Na 2 O 0.98 0.34 0.09 0.45 0.23 0.36
K∑ 2 O 0.10 0.02 0.01 0.03 0.05 0.05
99.2 100.1 99.9 100 100.4 99.5
Volatile elements
K (ppm) 854 180 83 200 420 500
Rb (ppm) 3.45 0.55 0.28 0.7 1.0 1.2
Cs (ppb) 279 18 12 20 40 30
Moderately volatile element
Mn (ppm) 2940 1000 1200 570 2150 2080
Moderately refractory element
Cr (ppm) 3975 3000 4200 800 5260 3030
Refractory elements
Sr (ppm) 11.9 17.8 30 130 101 121
U (ppb) 12.2 18 30 80 220 130
La (ppm) 0.367 0.55 0.90 2.0 6.0 5.22
Eu (ppm) 0.087 0.13 0.21 1.0 0.84 1.37
V (ppm) 85 128 150 30 175 50
Siderophile elements
Ni (ppm) 16500 2000 400 100 64 2
Ir (ppb) 710 3.2 0.01 — 0.02 0.04
Mo (ppb) 1380 59 1.4 5 50 50
Ge (ppm) 48.3 1.2 0.0035 0.02 0.003 0.003

aElemental abundances in Cl chondrites (volatile=primitive solar nebula). Earth mantle+crust=primitive Earth
mantle; bulk Moon; average lunar highland crust; low-Ti mare basalt (12002) and high-Ti mare basalt (70215). Both of these
later samples are probably primary basaltic magmas. Data sources from Taylor (1982) and Hartmann et al. (1986).

ages of 4440±20 million years and 4460±40 million
years have been obtained, and their average of 4450 mil-
lion years is taken to represent the crystallization age of
ferroan anorthosites from the lunar magma ocean and the
flotation of the feldspathic highland crust as “rockbergs.”
Alternatively, this date may represent the “isotopic closure
age” during cooling of the crust.


8.2 Mg Suite


The Mg suite comprises norites, troctolites, dunites, spinel
troctolites, and gabbroic anorthosites. They are character-
ized by higher, and so more primitive, Mg/ (Mg+Fe^2 +)
ratios compared to the ferroan anorthosites. They range in


age from about 4.44 billion years down to about 4.2 billion
years, but typical ages are 100–200 million years younger
than those of the ferroan anorthosites. The Mg suite is pet-
rographically distinct from the older ferroan anorthosites
and does not appear to be related directly to the crystal-
lization from the magma ocean. It makes up a minor but
significant proportion (perhaps 10%) of the highland crust
and has two distinct and contradictory components in terms
of conventional petrology. It is Mg-rich, and so primitive
in terms of igneous differentiation, but also contains high
concentrations of incompatible elements, typical or highly
evolved or differentiated igneous systems. These charac-
teristics point to an origin by mixing of these two distinct
components.
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