CK-12-Chemistry Intermediate

(Marvins-Underground-K-12) #1

http://www.ck12.org Chapter 25. Organic Chemistry


FIGURE 25.15


An alternate system for naming di-substituted benzene rings uses three different prefixes:ortho,meta, andpara. If
two groups areorthoto one another, they are on adjacent carbon atoms.Metapositioning refers to a 1,3 arrangement,
andparasubstituents are in a 1,4 arrangement. Shown below are the three possibilities for dimethylbenzene.


Lastly, a benzene ring missing one hydrogen atom (−C 6 H 5 ) can itself be considered the substituent on a longer chain
of carbon atoms. That group is called aphenylgroup, so the molecule below is called 2-phenylbutane.

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