SAT Subject Test Chemistry,10 edition

(Marvins-Underground-K-12) #1
rate    =   (130)(0.2)^2 (0.03) =   0.156
Again, even if we had not known what the rate constant is, we would not need to
calculate it explicitly for this problem. If [SO 3 ] were raised to 0.2 in trial 4, it would have
been doubled. Therefore the rate would be quadrupled, and would equal 4 × 0.039 =
0.156.

6 . B
The activation energy is the minimum amount of energy needed for a reaction to proceed. The
activation energy for the reverse reaction is the change in potential energy between the
products and the transition state indicated by arrow B. A is the overall (thermodynamic)
energy change of the reaction. C is the activation energy for the forward, not the reverse,
reaction.


7 . The best way to visualize the solution to this set of problems is to draw a diagram.


ΔE  =   Activation  Energy  (forward)   –   Activation  Energy  (reverse)

=   78  kJ  –   300 kJ  =   −222    kJ.
And since

ΔE  =   Energy  (products)  −   Energy  (reactants)

−222    kJ  =   25  kJ  −   X   kJ,

X   =   247 kJ  =   energy  of  reactants.

A.

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