MCAT Organic Chemistry Review 2018-2019

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14 .    Which   reactant    could   be  combined    with    butanol to  form    butyl   acetate?

(A) (CH 3 CO) 2 O and catalytic acid
(B) (CH 3 CH 2 CO) 2 O and catalytic acid
(C) CH 3 CH 2 CONH 2 and catalytic acid
(D) CH 3 CONH 2 and catalytic acid


15 .    Why should  esterification  reactions   NOT be  carried out in  water?

(A) Carboxylic acids, from which esters are made, are generally insoluble in water.
(B) The polar nature of water overshadows the polar nature of the leaving group.
The extensive hydrogen bonding of water interferes with the nucleophilic
addition mechanism.


(C)


Water   molecules   would   hydrolyze   the desired products    back    into    the parent
carboxylic acid.

(D)

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