Encyclopedia of Environmental Science and Engineering, Volume I and II

(Ben Green) #1
402

F

FLUIDIZED BED COMBUSTION


INTRODUCTION

The technology for reacting suspended coal particles with
a gas fl owing through them dates back to the 1920s when
the Winkler gas generator was developed in Germany. The
petroleum industry was responsible for the commercial
expansion of fl uidization techniques in the U.S. (1940s),
particularly in the use of solids which catalytically crack
vaporized heavy oils to produce gasoline and other petro-
leum fuels. The application of fl uidized bed combustion
(FBC) technology (to various solid fuels) is widespread in
the U.S. and in other countries for all types of industrial
processes. More than 350 atmospheric fl uidized bed units
are operating in North America, Europe and Asia. FBC is
part of the answer to the question—how do we control our
major emissions from coal sources? Briefl y an FBC boiler is
a fi nely divided bed of solid fuel particles in admixture with
limestone particles which are suspended or conveyed by
primary combustion air moving in the vertical upward direc-
tion. The limestone reacts with sulfur dioxide to remove it
from the fl ue gas. The low uniform temperature (ca 1550F)
has a benefi cial effect on nitrogen oxide suppression. The
emission from coal combustion schemes of nitrogen oxides
(NO x ) and sulfur dioxide (SO 2 ), together with carbon oxides
(CO and CO 2 ), particulate matter and solid wastes must
always be compared when evaluating various alternative
schemes. The potential consequences of gaseous emissions,
include the greenhouse effect and acid rain, which have
received much publicity in recent years. The practical FBC
limit of SO 2 removal is currently about 95%. Nitrogen oxide
formation is lower than with conventional pulverized coal
(PC) boiler NO x control.

TYPES OF FLUIDIZED BED COMBUSTORS (FBCS)

FBCs are generally referred to as either circulating (CFB) or
bubbling beds. However, the bubbling type may be classifi ed
according to whether reaction takes place at atmospheric
(AFB) or under pressurized conditions (PFB).

A. Circulating Fluidized Bed
Combustors

In the basic CFB combustor, coal or some other type of fossil
fuel, e.g., natural gas or petroleum, is injected into the com-
bustor together with a calcium based material such as lime-
stone or dolomite to be used as a sorbent for SO 2. The bed
material is entrained by fl uidizing air usually in the velocity
range of 12–30 ft/sec. The entrained material is forced into
a refractory-lined cyclone located between the combustor
and the convective pass. The separated larger particles are
reintroduced at the bottom of the combustion chamber or,
as in some designs, to an external heat exchanger. The mean
bed particle size is usually between 50 and 300 microns.
Combustion temperature will vary but generally is kept
between 1550F and 1650F.^1 In this temperature range SO 2
sorption is optimized and the formation of nitrogen oxides
is minimized.
The heavier solids fall to the bottom of the cyclone and
are recirculated at a ratio of between 15:1 and 100:1 (solids to
feed). The carbon content of the bed is usually about 3–4%.
Calcium sulfate, ash, and calcined limestone make up the
bulk of the recirculated material. The fl ue gas exits the top of
the cyclone, travels through the convective pass and typically
goes into an economizer (heat exchanger—superheated steam
produced) and into a tubular air preheater. From there the gas
may enter an electrostatic precipitator or a bag house dust
collector (for removal of fi ne particulate matter from the gas).
An induced draft fan is fi nally employed to force the gas up a
stack and into the atmosphere.
Combustion air is provided at two levels of the combus-
tor. Primary air enters through the bottom of the combustor
and is evenly distributed by a gas distributor plate. Secondary
air enters through a number of ports in the sidewalls of the
combustor. Hence, there are two staged areas of combustion
within the combustor. In the lower combustor, combustion
takes place under reducing conditions. In the upper com-
bustor nitrogen oxides are further reduced as is particulate
matter. The admission of secondary air is also benefi cial
in controlling the temperature of the combustor as well as in

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