536 INDUSTRIAL WASTE MANAGEMENT
Power Generation Industry
The power generation industry uses large volumes of
water for cooling purposes. It is estimated that total cool-
ing water demand for power generation is in excess of
400 billion cubic meters per year. This is approximately
one-fifth of the total runoff in the United States.^33 Direct
discharge of cooling water in streams, lakes, and estuaries
has an impact on water quality and the ecosystem in three
ways: it pollutes the water thermally, it subjects aquatic
organisms to a variety of physical stresses as it is pumped
through the plant, and it pollutes the water chemically.
Types of Cooling Systems
Basically, there are three ways of dissipating heat: once
through cooling systems, cooling ponds, and cooling towers.
The average condenser water requirement and consumptive
use for different cooling systems are summarized below:^36
Condenser requirement 120 liters per KWH
Consumptive use:
once through 0.7 liter per KWH
cooling ponds 1.0 liter per KWH
cooling tower 1.4 liter per KWH
A general discussion on three types of heat dissipating
systems is given below:^37
Once Through Cooling The most common and least
expensive method for removing heat from power plant
condensers is a once-through-cooling system. The system
requires large intake structures and has the largest environ-
mental impact. Aquatic organisms are forced through the
condenser tubes resulting in high mortality. The 2 to 5°C
warmer discharge upsets stratification, lowers dissolved
oxygen, increases the metabolic rate of aquatic animals, and
increases undesired bacteria.
Cooling Ponds The cooling water is circulated through
cooling ponds in a closed-loop. Cooling occurs by evaporation,
conduction, and long-wave radiation. Land area of the ponds
are generally 0.5–1 hectare/MW.
Cooling Towers Cooling towers are used to eliminate
discharge of heated water into natural bodies of water.
There are two types of cooling towers: natural-draft and
mechanical-draft. Natural-draft cooling towers rely on
natural air circulation to dissipate waste heat to the atmo-
sphere. The mechanical-draft cooling towers use induced
drafts to promote evaporative heat transfer. Both require
heat transfer between water and air. Dry cooling towers use
a temperature driving force between the water inside the
tubes and air flowing past the tubes.
Wastewater Treatment
Chemical discharges from the power-generation industry result
from makeup water treatment; chemicals added to plant cool-
ing water or steam generator; products of corrosion, erosion,
wear, or chemical reaction from plant system; and residuals
from pollution control equipment. The chemicals generally
controlled in effluent discharge permits are: pH, PCBs, TSS,
oil and grease, heavy metals, free and total residual chlorine,
phosphorus, and corrosion inhibitors.^34 Treatment methods
generally used for removal of contaminants include: neutral-
ization, coagulation, and precipitation of corrosion inhibitors,
TSS, heavy metals and phosphorus; flotation or American
Petroleum Institute (API) separator for oil and grease; ion-
exchange or reverse osmosis for TDS control; and evaporation
for concentration and residue recovery and disposal.
REFERENCES
- Henry Lee, Legislation and Standards: Status, Trends Significance,
Chapter 1, “Industrial Wastewater Management Handbook”, H.S. Azad
(Editor), McGraw-Hill Book Co., New York, 1976. - Qasim, S.R., Wastewater Treatment Plant: Planning Design and Opera-
tion, Technomic Publishing Company, Inc. Lancaster, PA, 1994. - Federal Water Pollution: Control Act Amendment of 1972 (PL 92-500),
92nd U.S. Congress, October 18, 1972. - Clean Water Act (PL 95-217), 95th U.S. Congress December 27, 1977.
- Wentz, C.A., Hazardous Waste Management, McGraw-Hill Book Co.,
New York, 1995.
TABLE 8
Origin, characteristics, and treatment of wastes in four major metal industries
Industries Producting Wastes Origin of Major Wastes Major Characteristics Major Treatment and Disposal Methods
Steel Coking of coal, washing of
blast-furnace flue gases,
and pickling of steel
Low pH, acids, phenol, ore, coke,
limestone, alkali, oils, mill
scale, and fine suspended solids
Neutralization, recovery and reuse,
chemical coagulation
Iron-foundry products Wasting of used sand by
hydraulic discharge
High suspended solids, mainly
sand; some clay and coal
Selective screening, drying of reclaimed
sand
Metal container Cutting and lubricating metals,
cleaning can surface
Metal fines, lubricating oils,
variable pH, surfactants,
dissolved metals
Oil separation, chemical precipitation,
collection and reuse, lagoon storage.
Final carbon adsorption
Metal-plated products Stripping of oxides, cleaning and
plating of metals
Acid, metals, toxic, low volume,
mainly mineral matter
Alkaline chlorination of cyanide;
reduction and precipitation of
chromium; lime precipitation of
other metals
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