Encyclopedia of Environmental Science and Engineering, Volume I and II

(Ben Green) #1

656 MANAGEMENT OF SOLID WASTE


take advantage of the economics of size. However, small skid-
mounted units with capacities in the range of 20 ton to 50 tons
per day are available at a cost which will make central incinera-
tion for smaller communities economical possible. The first of
these units that met most air pollution codes was marketed by
Combustion Engineering in the late ’60s. It was ahead of its
time and did not enjoy success. However, similar size units with
energy recovery are now finding a good acceptability. Another
development will be the installation of more combined sewage
sludge-refuse incineration facilities using the Nichols multiple
earth rotating grid or similar installations.
Rotary kiln incinerators have been successfully utilized
in handling mixed wastes, often predominantly industrial
wastes. They are particularly useful where long residence
times are required to insure complete combustion. Their
disadvantages center primarily around high maintenance
costs. One of these incinerators has been in operation at Dow
Chemical, Midland, Michigan for almost 30 years.
Incineration in fluidized beds was demonstrated by
Black and Clawson in a facility in Franklin, Ohio, as well as
by Combustion Power Co. which combined a fluid bed com-
bustor with a gas-turbine generator to produce power from
400 tons per day of refuse. The latter demonstrations had
technical difficulties and fluidized bed technology has not
been commercialized.
Numerous on-site incinerators are operated with satis-
factory results for the reduction of industrial wastes. These
facilities are usually specially designed to handle one type of
refuse. Typical materials that are incinerated include plastics,
rubber, wood scrap and paper. The economics of waste recov-
ery are changing so that often these materials are no longer
burned. For example wood chips and sawdust at sawmills
are often sent to paper-mills or composition board producers
as feed, where formerly they were burned. Insulated copper
wire and automobiles are incinerated to remove the organic
components prior to recovery of the metal. Special liquid

TABLE 17
Incinerator effl uent gas composition d

Combustion Products
Feed Product Gas composition vol. %
Component Wt. % Excess air component 0% 50%

Carbon 30.0 CO 2 16.00 9.86
Hydrogena 6.1 H 2 O 19.5 12.04
Oxygene 43.3 O 2 — 7.94
NOx — ~700 ppmb
Nitrogen 0.5 N 2 64.5 70.15
Sulfur 0.1 SO 2 0.02 0.01
Noncombustible 20.0c —— —

a Includes moisture of 20%.
b Not computed.
c No combustion of metal assumed, in actuality same takes place.
d Excluding particular matter.
e Based on theoretical required less O 2 contained in feed.

a potential recovery of $10 to $15 per ton or refuse for the
steam sold.
In addition to the installation of units with waste heat
recovery facilities the trend will be to longer installations to

TABLE 18
Incinerator stack gas contaminants

Component Amounts reported

Organic Acids
Formic 25–133 ppm (31)
Palmitic 0.6 lbs/ton of refuse (32)
Acetic (all organics) 40–600 mg m^3 (33)
Esters
Methyl acetate 5–137 ppm (32)
Ethyl acetate —
Aldehydes
Acetaldehyde 2.8  10 –4 (33)
Formaldehyde 1.1 lbs/ton refuse (32)
Hydrocarbons 4 mgm/gm of particulate (29a)
Halogenated Hydrocarbons
(depends on plastics and aerosols) 6–120 mg m^3 (33)
0.44–10 ppm (31)
0.3 lbs/ton refuse (32)
Ammonia 0.15–1.5 ppm (31)
Nitrogen Dioxide 0.15–5 mg m^3 (33)
Nitrogen Trioxide 4–100 mg/m^3 (33)
HCl 300–1200 mg/kg refuse (33)
30–350 mg/m^3 (33)
SO 2 0.25–1.2 ppm (31)
1.9 lbs/ton refuse (32)

a When burning rubber.

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