Mathematical Methods for Physics and Engineering : A Comprehensive Guide

(lu) #1

QUANTUM OPERATORS


For a particle of massmmoving in a one-dimensional potentialV(x), prove
Ehrenfest’s theorem:
d〈px〉
dt

=−



dV
dx


and

d〈x〉
dt

=


〈px〉
m

.


19.4 Show that the Pauli matrices


Sx=^12 

(


01


10


)


, Sy=^12 

(


0 −i
i 0

)


, Sz=^12 

(


10


0 − 1


)


,


which are used as the operators corresponding to intrinsic spin of^12 in non-
relativistic quantummechanics, satisfyS^2 x=S^2 y=S^2 z=^14 ^2 I, and have the
same commutation properties as the components of orbital angular momentum.
Deduce that any state|ψ〉represented by the column vector(a, b)Tis an eigenstate
ofS^2 with eigenvalue 3^2 /4.
19.5 Find closed-form expressions for cosCand sinC,whereCis the matrix


C=


(


11


1 − 1


)


.


Demonstrate that the ‘expected’ relationships

cos^2 C+sin^2 C=I and sin 2C=2sinCcosC
are valid.
19.6 OperatorsAandBanticommute. Evaluate (A+B)^2 nfor a few values ofnand
hence propose an expression forcnrin the expansion


(A+B)^2 n=

∑n

r=0

cnrA^2 n−^2 rB^2 r.

Prove your proposed formula for general values ofn, using the method of
induction.
Show that

cos(A+B)=

∑∞


n=0

∑n

r=0

dnrA^2 n−^2 rB^2 r,

where thednrare constants whose values you should determine.

By taking asAthe matrixA=

(


01


10


)


, confirm that your answer is
consistent with that obtained in exercise 19.5.
19.7 Expressed in terms of the annihilation and creation operatorsAandA†discussed
in the text, a system has an unperturbed HamiltonianH 0 =ωA†A. The system
is disturbed by the addition of a perturbing HamiltonianH 1 =gω(A+A†),
wheregis real. Show that the effect of the perturbation is to move the whole
energy spectrum of the system down byg^2 ω.
19.8 For a system ofNelectrons in their ground state| 0 〉, the Hamiltonian is


H=


∑N


n=1

p^2 xn+p^2 yn+p^2 zn
2 m

+


∑N


n=1

V(xn,yn,zn).

Show that

[


p^2 xn,xn

]


=− 2 ipxn, and hence that the expectation value of the
double commutator[[x, H],x],wherex=

∑N


n=1xn,isgivenby

〈 0 |[[x, H],x]| 0 〉=

N^2


m

.

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