Physical Chemistry Third Edition

582 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics Find the rate law for the oxidation of CO. Use the st ...

13.2 Competing Mechanisms and the Principle of Detailed Balance 583 [E]tot 1. 67 × 10 −^5 mol L−^1 ,Km 4. 0 × 10 −^6 mol L−^1 ...

584 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics Let us see what would be the consequence of assuming ...

13.3 Autocatalysis and Oscillatory Chemical Reactions 585 to averages over microstates. From our discussion of statistical entro ...

586 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics corresponds to the mechanism (1) A+F
C (2) C→2F (13.3 ...

13.3 Autocatalysis and Oscillatory Chemical Reactions 587 Exercise 13.13 Solve the simultaneous equations in Eq. (13.3-6) to obt ...

588 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics reverse steps are included, the overall reaction corr ...

13.4 The Reaction Kinetics of Polymer Formation 589 a single curve, called alimit cycle. There is also a simplified mechanism wi ...

590 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics Synthetic polymers are also classified by the type of ...

13.4 The Reaction Kinetics of Polymer Formation 591 We assume that the reaction is first order in the diacid, first order in the ...

592 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics Equation (13.4-9) agrees with experiment fairly well ...

13.4 The Reaction Kinetics of Polymer Formation 593 From Eqs. (13.4-7) and (13.4-15), we can write an equation for the time depe ...

594 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics (b) 0.006 0.005 0.004 0.003 0.002 0.001 0 0 500 1000 ...

13.5 Nonequilibrium Electrochemistry 595 molecules with the following percentages and molecular masses: 10.00% 5000 amu 25.00% 1 ...

596 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics Electrolytic Cells Near Equilibrium Figure 13.13 sche ...

13.5 Nonequilibrium Electrochemistry 597 other and move to the surface of the electrode in order to be as far from each other as ...

598 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics




0 1020304050607080 1.0 0.8 0.6 0.4 0.2 0.0 ...

13.5 Nonequilibrium Electrochemistry 599 κ(1. 602 × 10 −^19 C) ( 2(6. 022 × 1023 mol−^1 )(997 kg m−^3 )(0.0200 mol kg−^1 ) (6. ...

600 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous Topics would correspond to a current passing through the ele ...

13.5 Nonequilibrium Electrochemistry 601 For a planar electrode and for the assumed concentration profile of Figure 13.16, Fick’ ...