Physical Chemistry Third Edition

Contents xiii

     - Entropy 3.2 The Mathematical Statement of the Second Law:

• 3.3 The Calculation of Entropy Changes


• 3.4 Statistical Entropy
  
  
  • Entropies 3.5 The Third Law of Thermodynamics and Absolute
  
  
  
  


• Chapter 4 The Thermodynamics of Real Systems
  
  
  • The Gibbs and Helmholtz Energies 4.1 Criteria for Spontaneous Processes and for Equilibrium:
  
  
  • 4.2 Fundamental Relations for Closed Simple Systems
  
  
  • 4.3 Additional Useful Thermodynamic Identities
  
  
  • 4.4 Gibbs Energy Calculations
  
  
  • 4.5 Multicomponent Systems
  
  
  • 4.6 Euler’s Theorem and the Gibbs–Duhem Relation
  
  
  
  


• Chapter 5 Phase Equilibrium
  
  
  • 5.1 The Fundamental Fact of Phase Equilibrium
  
  
  • 5.2 The Gibbs Phase Rule
  
  
  • 5.3 Phase Equilibria in One-Component Systems
  
  
  • 5.4 The Gibbs Energy and Phase Transitions
  
  
  • 5.5 Surfaces in One-Component Systems
  
  
  • 5.6 Surfaces in Multicomponent Systems
  
  
  
  


• Chapter 6 The Thermodynamics of Solutions
  
  
  • 6.1 Ideal Solutions
  
  
  • 6.2 Henry’s Law and Dilute Nonelectrolyte Solutions
  
  
  • 6.3 Activity and Activity Coefficients
  
  
  • 6.4 The Activities of Nonvolatile Solutes
  
  
  • 6.5 Thermodynamic Functions of Nonideal Solutions
  
  
  • 6.6 Phase Diagrams of Nonideal Mixtures
  
  
  • 6.7 Colligative Properties
  
  
  
  


• Chapter 7 Chemical Equilibrium
  
  
  • Constant 7.1 Gibbs Energy Changes and the Equilibrium
  
  
  • 7.2 Reactions Involving Gases and Pure Solids or Liquids
  
  
  • 7.3 Chemical Equilibrium in Solutions
  
  
  • 7.4 Equilibria in Solutions of Strong Electrolytes
  
  
  • 7.5 Buffer Solutions
    
    
    • The Principle of Le Châtelier 7.6 The Temperature Dependence of Chemical Equilibrium.
    
    
    
    
  
  
  • 7.7 Chemical Equilibrium and Biological Systems
  
  
  
  


• Chapter 8 The Thermodynamics of Electrochemical Systems
  
  
  • 8.1 The Chemical Potential and the Electric Potential
  
  
  • 8.2 Electrochemical Cells
  
  
  • 8.3 Half-Cell Potentials and Cell Potentials
    
    
    • of Electrolytes 8.4 The Determination of Activities and Activity Coefficients
    
    
    
    
  
  
  • 8.5 Thermodynamic Information from Electrochemistry
    
    
    • 13.5 Nonequilibrium Electrochemistry
      
      
      • Mechanisms 13.6 Experimental Molecular Study of Chemical Reaction
      
      
      
      
    
    
    
    
  
  
  • Part 3 The Molecular Nature of Matter
  
  
  
  


• Chapter 14 Classical Mechanics and the Old Quantum Theory
  
  
  • 14.1 Introduction
  
  
  • 14.2 Classical Mechanics
  
  
  • 14.3 Classical Waves
  
  
  • 14.4 The Old Quantum Theory
  
  
  • the Schrödinger Equation Chapter 15 The Principles of Quantum Mechanics. I. De Broglie Waves and
    
    
    • 15.1 De Broglie Waves
    
    
    • 15.2 The Schrödinger Equation
    
    
    • 15.3 The Particle in a Box and the Free Particle
    
    
    • 15.4 The Quantum Harmonic Oscillator
    
    
    
    
  
  
  • Quantum Mechanics Chapter 16 The Principles of Quantum Mechanics. II. The Postulates of
    
    
    • 16.1 The First Two Postulates of Quantum Mechanics
      
      
      • Variables 16.2 The Third Postulate. Mathematical Operators and Mechanical
      
      
      
      
    
    
    • 16.3 The Operator Corresponding to a Given Variable
    
    
    • 16.4 Postulate 4 and Expectation Values
    
    
    • 16.5 The Uncertainty Principle of Heisenberg
      
      
      • State of a System 16.6 Postulate 5. Measurements and the Determination of the
      
      
      
      
    
    
    
    
  
  
  
  


• Chapter 17 The Electronic States of Atoms. I. The Hydrogen Atom
  
  
  • 17.1 The Hydrogen Atom and the Central Force System
    
    
    • Momentum 17.2 The Relative Schrödinger Equation. Angular
    
    
    • The Energy Levels of the Hydrogen Atom 17.3 The Radial Factor in the Hydrogen Atom Wave Function.
    
    
    
    
  
  
  • 17.4 The Orbitals of the Hydrogen-Like Atom
  
  
  • 17.5 Expectation Values in the Hydrogen Atom
  
  
  • 17.6 The Time-Dependent Wave Functions of the Hydrogen Atom
    
    
    • “Spin” 17.7 The Intrinsic Angular Momentum of the Electron.
    
    
    
    
  
  
  • for Multielectron Atoms Chapter18 TheElectronicStatesofAtoms.II.TheZero-OrderApproximation
    
    
    • 18.1 The Helium-Like Atom
      
      
      • Principle 18.2 The Indistinguishability of Electrons and the Pauli Exclusion
      
      
      
      
    
    
    • 18.3 The Ground State of the Helium Atom in Zero Order
    
    
    • 18.4 Excited States of the Helium Atom
    
    
    • 18.5 Angular Momentum in the Helium Atom
    
    
    
    
  
  
  
  


• 28.5 The Structure of Liquids
  
  
  • Liquids 28.6 Approximate Theories of Transport Processes in
  
  
  
  


• 28.7 Polymer Conformation


• 28.8 Polymers in Solution


• 28.9 Rubber Elasticity


• 28.10 Nanomaterials


• Appendices


• A. Tables of Numerical Data
  
  
  • B. Some Useful Mathematics
  
  
  • C. A Short Table of Integrals
  
  
  • D. Some Derivations of Formulas and Methods
  
  
  • E. Classical Mechanics
  
  
  • F. Some Mathematics Used in Quantum Mechanics
  
  
  • G. The Perturbation Method
  
  
  • H. The Hückel Method
  
  
  • I. Matrix Representations of Groups
  
  
  • J. Symbols Used in This Book
    
    
    • Numerical Problems K. Answers to Numerical Exercises and Odd-Numbered
    
    
    
    
  
  
  
  


• Index