Physical Chemistry Third Edition

(C. Jardin) #1

7


Chemical Equilibrium


PRINCIPAL FACTS AND IDEAS


  1. The principles of thermodynamics determine the state of chemical
    equilibrium for any reaction.

  2. The equilibrium constant expression of elementary chemistry is equal to a
    constant at constant temperature when it is expressed in terms of
    activities.

  3. The principle of Le Châtelier can predict how a chemical system at
    equilibrium responds to changes in temperature, pressure, or amounts of
    substances.

  4. The coupling of biochemical reactions can be understood through
    thermodynamics and the use of postulated mechanisms.


303
Free download pdf