Physical Chemistry Third Edition

(C. Jardin) #1

10


Transport Processes


PRINCIPAL FACTS AND IDEAS


  1. The macroscopic description of nonequilibrium states of fluid systems
    requires independent variables to specify the extent to which the system
    deviates from equilibrium and dependent variables to express the rates of
    processes.

  2. The three principal transport processes are heat conduction, diffusion,
    and viscous flow.

  3. Each transport process is described macroscopically by an empirical
    linear law.

  4. Molecular theories of transport processes in dilute gases are based on gas
    kinetic theory.

  5. Transport processes in liquids are visualized as the motion of molecules
    from one “cage” to another with the cages being made up of neighboring
    molecules.

  6. The electrical conductivity of solutions of ions can be understood on the
    basis of ionic motion in an electric field.


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