Physical Chemistry Third Edition

(C. Jardin) #1

17


The Electronic States of Atoms.


I. The Hydrogen Atom


PRINCIPAL FACTS AND IDEAS


  1. The hydrogen atom is an example of a central-force system
    (a two-particle system in which the potential energy depends only on the
    distance between the two particles).

  2. The Schrödinger equation for the hydrogen atom can be separated into
    one equation for the motion of the center of mass and one equation for the
    motion of the electron relative to the nucleus.

  3. The relative Schrödinger equation can be solved in spherical polar
    coordinates by separation of variables, assuming that
    ψR(r)Θ(θ)Φ(φ). These wave functions are called orbitals.

  4. The energy eigenvalues for the relative motion are the same as in the
    Bohr theory.

  5. The square of the orbital angular momentum of the electron and one
    component of this angular momentum can have predictable values if a
    hydrogen atom is in a state corresponding to an energy eigenfunction.
    The angular momentum values are different from the Bohr theory.

  6. Electrons have intrinsic (spin) angular momentum in addition to the
    angular momentum of orbital motion.


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