THERMODYNAMICS AND STATISTICAL PHYSICS^199For J = 1,c) For largeHthe magnetization saturatesIt is convenientto define theso-calledBrillouinfunction [Brillouin,
Journal de Physique 8 , 74 (1927)] in such a way thatSo,For smallH, we can expandcothSo,The saturationvalue(S.4.81.10) corresponds to aclassicaldipole per
atom, where all the dipoles are aligned along the direction of H, whereas the
value at small magnetic field H (S.4.81.11) reflects a competition between
order(H)and disorder