The Chemistry Maths Book, Second Edition

(Grace) #1

4.12 The differential 119


Derivatives with respect to time are sometimes written in a ‘dot notation’:


6

(4.27)


0 Exercise 87


Angular motion


Consider a body moving in a circle of radius r. Let O be a


fixed point on the circle and let the position of the body


at time tbe given by the angle θ(Figure 4.13). The rate of


change of θwith respect to time is called the angular


velocity:


(4.28)


In addition, because arc length sis related to subtended


angle θbys 1 = 1 rθ, we haveK1= 1 r 4 or


v 1 = 1 rω (4.29)


for the relation between linear and angular velocities for motion in a circle (see


Chapter 16 for a more general discussion of velocity in terms of vectors). The angular


acceleration is 71 = 15.


0 Exercise 88


4.12 The differential


The first derivative of a functiony 1 = 1 f(x)is defined by equation (4.8),


and, as has been emphasized before, the symboldy 2 dxdoes not mean the quantity dy


divided by dx, but represents the value of the limit; in this sensef′(x), or y′, is a better


symbol for the derivative. It is nevertheless tempting to write


dy 1 = 1 f′(x) 1 dx


and, when properly interpreted, this is a useful way of describing changes.


dy


dx


fx


y


x


fx x


xx


= ′ =








=






→→


( ) lim lim


()


∆∆





00


−−












fx


x


()



angular velocity==




==



ω


θθ


lim θ


∆t t


d


0 dt





vv== , ==



x

dx


dt


x


dx


dt


2

2

6

In his 1671 paper on the calculus, Methodus fluxionum et serierum infinitorum, Newton considered variables


like xand yas flowing quantities, or fluents, and wrote Hand Ifor their rates of change, or fluxions. Dotted fluxions


were still being used by English mathematicians when the Cambridge undergraduates George Peacock (1791–1858),


John Herschel (1792–1871), and Charles Babbage (1792–1871) founded the Analytical Society in 1813. One of the


aims of the Society was to promote ‘the principles of pure d-ism as opposed to the dot-age of the university’.


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t


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∆ θ


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Figure 4.13

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