The Chemistry Maths Book, Second Edition

(Grace) #1

160 Chapter 5Integration


5.9 Exercises


Section 5.2


Evaluate the indefinite integrals:








































Evaluate the indefinite integrals subject to the given conditions:



  1. ; y 1 = 1 0 whenx 1 = 13 12. ; y 1 = 1 0 whenx 1 = 1 π 24

  2. ;I 1 = 1 4whenx 1 = 12 14. ;I 1 = 1 3whenx 1 = 11

  3. ; I 1 = 1 0 whenx 1 = 10


Section 5.3


Evaluate the definite integrals:































  1. (i)Show that the rate equation of a first-order decomposition reaction


can be written in the logarithmic form


(ii)Integrate this equation with respect totover the range 0 to t, and show that


25.The Clausius–Clapeyron equation for liquid–vapour equilibrium is


If the enthalpy of vaporization, ∆H


vap

, is constant in the temperature rangeT


1

toT


2

show, by integrating both sides of the equation with respect to T, that


wherep


1

1 = 1 p(T


1

)andp


2

1 = 1 p(T


2

).


ln


p


p


H


RTT


2

112

11










=












vap

dp


dT


H


RT


ln


=



vap

2

ln


()


()


() ( )


xt


x


kt x t x e


kt

0


0










=− =



and


dx


dt


k


ln


=−


dx


dt


=−kx


Z


−π 4

0

Z sin 2 xdx


0

cos 3


π

Z θθd


0

π 2

Z cosθθd


1

5

3

edt


−t

Z


2

3

2


dv


v+


Z


1

2

3

du


u


Z


3

5

Z dx



+

++


1

1

2

() 234 xxdx


Ixedx


x

=−+ −








Z 44 2


1


2


2

cos


I


xx


x


= dx


++


Z


321


2

2

Ixxdx=++Z()523


4

yxd=Zcos4 x


yxdx=Z


2

Z


dx


3 −x


Z


dx


x− 1


Zedx


− 2 x

Zedx


3 x

Zsin 4xdx


Zxdx


− 13

Z


dx


x


3

Zxdx


23

Zxdx


3

Z 2 dx

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