The Chemistry Maths Book, Second Edition

(Grace) #1

6.5 Reduction formulas 177


More important still, the recurrence relation is ideally suited for the computation of


one or several members of a family of integrals.


Reduction formulas are particularly simple for some important definite integrals in


the physical sciences. For example, the integral


(a 1 > 1 0) (6.16)


where nis a positive integer or zero, occurs in the quantum-mechanical description of


the properties of the hydrogen atom. Integration by parts gives


Whenn 1 ≠ 10 , the quantitye


−ar

1 r


n

is zero at both integration limits,r 1 = 10 andr 1 → 1 ∞.


Therefore


n 1 ≥ 11


and it follows that


(6.17)


wheren! 1 = 1 n(n 1 − 1 1)(n 1 − 1 2)1-1 1 is the factorial of n.


EXAMPLE 6.14Determine a reduction formula for where nis a


positive integer.


Write the integrand as cos


n− 1

1 x 1 cos 1 x, and let u 1 = 1 cos


n− 1

1 x and Then


v 1 = 1 sin 1 x, and


and, becausesin


2

1 x 1 = 111 − 1 cos


2

1 x,


= 1 cos


n− 1

1 x 1 sin 1 x 1 + 1 (n 1 − 1 1)I


n− 2

1 − 1 (n 1 − 1 1)I


n

I x xn xdxn xd


n

nnn

=+− −−


−−

cos sin ( ) cos ( ) cos


12

11 ZZxx


Ixxn xxdx


n

nn

=+−


−−

cos sin ( ) cos sin


122

1 Z


d


dx


x


v


=cos.


Ixdx


n

n

=Zcos


Ierdr


n


a


n

ar n

n

==


!



+

Z


0

1


I


n


a


I


nn

=,


− 1

I


a


er


n


a


I


n

ar n

n

=− +














0

1

1



Ierdr


n

ar n

=



Z


0

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