The Chemistry Maths Book, Second Edition

(Grace) #1

264 Chapter 9Functions of several variables


A special case of the total derivative (9.21) is obtained if tis replaced by x. Then


y 1 = 1 y(x)is an explicit function of xandz 1 = 1 f(x, y(x))can be treated as a function of


the single variable x. Then, from (9.21),


(9.23)


We note that ifx 1 = 1 x(t)then this total derivative with respect to xis related to the total


derivative (9.21) with respect to tby the chain rule:


(9.24)


EXAMPLE 9.14


(i) Givenz 1 = 1 x


2

1 + 1 y


3

, wherey 1 = 112 x, finddz 2 dx. Then, (ii) ifx 1 = 1 e


t

, finddz 2 dt.


(i) By equation (9.23), since ,


(ii) Ifx 1 = 1 e


t

then and


This is identical to the result of Example 9.12, sincex 1 = 112 y.


0 Exercise 41


Walking on a contour


Consider changes in xand ythat leave the value of the functionz 1 = 1 f(x, y)unchanged.


In Figure 9.6, the plane ABC is parallel to the xy-plane, so that all points on the curve


APB on the representative surface are at constant value of z. The displacement P to Q


therefore lies on a contour of the surface. Then, by (9.16),


(9.25)


∆= ≈






















z


z


x


x


z


y


y


yx


0 ∆∆


dz


dt


dz


dx


dx


dt


==− 23 xxy


24

dx


dt


ex


t

==,


dz


dx


z


x


z


y


dy


dx


= xy y xy










=+ 23 ×− =− 23


22 4

()( )


dy


dx


x


=− =−y


1


2

2

dz


dt


dz


dx


dx


dt


z


x


dx


dt


z


y


dy


yx


==









 +










ddx


dx


dt


dz


dx


z


x


z


y


dy


dx


yx


=





















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