The Chemistry Maths Book, Second Edition

(Grace) #1

270 Chapter 9Functions of several variables


wheref 1 = 1 f(x, y)is a function of the cartesian coordinates of a point in a plane. The


Laplace equation occurs in many branches of the physical sciences, and is the


fundamental equation in ‘potential theory’, when a physical system is described in


terms of a potential function; for example, the gravitational and electrostatic potential


functions in a region free of matter satisfy the Laplace equation in three dimensions


(see Chapter 10). The equation in two dimensions is important in flow theories; for


example in the theory of fluid flow and of heat conduction.


5

As in Example 9.17, the position of a point in a plane can be specified in terms


of the polar coordinates rand θ, wherex 1 = 1 r 1 cos 1 θandy 1 = 1 r 1 sin 1 θ. The functionf


can therefore be treated as a function of rand θ,f 1 = 1 f(r, θ), and equation (9.37) can


be transformed from an equation in cartesian coordinates to an equation in polar


coordinates by the method described in Example 9.17. Example 9.18 shows how this


is done, with result


The differential operator


(9.38)


(read as ‘del-squared’ or ‘nabla-squared’) is called the Laplacian operator(although


the symbol and the name are usually reserved for the three-dimensional form; see


Chapter 10). The Laplace equation is then



2

f 1 = 10 (9.39)


and a solution fof the equation as known as a harmonic function.


EXAMPLE 9.18The two-dimensional Laplacian in polar coordinates


By the first of equations (9.36) in Example 9.17,




=







f


x


f


rr


f


cos


sin


θ


θ


θ


=
















2

22

2

2

11


r


rr
r θ

∇=










2

2

2

2

2

xy










=
















=


2

2

2

2

2

22

2

2

11


0


f


x


f


y


f


r


r


f


r


r


f


θ


5

Pierre Simon de Laplace (1749–1827). His Traité de mécanique céleste(Treatise on celestial mechanics) in 5


volumes (1799–1825) marked the culmination of the Newtonian view of gravitation. Legend has it that whilst at


the École Militaire, where he taught elementary mathematics to the cadets, he examined, and passed, Napoleon in





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