The Chemistry Maths Book, Second Edition

(Grace) #1

304 Chapter 10Functions in 3 dimensions


and, after integration over the angles (see equation (10.13)),


(ii)


0 Exercises 23, 24


10.5 The Laplacian operator


The Laplacian operator in two dimensions was discussed in Section 9.6. The operator


in three dimensions is:


in cartesian coordinates,


(10.18)


in spherical polar coordinates,


(10.19a)


(10.19b)


The transformation from cartesian to spherical polar coordinates is achieved in


the same way as that described in Example 9.18 for the two-dimensional case. The


operator in spherical polar coordinates is usually quoted in the slightly more compact


form (10.19a), and the expanded form (10.19b) is obtained by use of the product rule


of differentiation. For example,


(10.20)


The Laplacian operator occurs in the equations of motion concerned with wave


motion and potential theory in both classical mechanics (as in Maxwell’s equations


11


2


2

2

2

2

2

2

r


r


r


f


r
r

r


f


r


r


f


r












=




















=










2

2

f 2


r


r


f


r


=


























2

22

2

22 22

21 1


r


rr


rr rθ


θ


θ


θ


cos


sin sin θθ φ




2

2

∇=

























2

2

2

2

11


r


r


r


r
r sin

sin


θ


θ


θ


θ











1


22

2

2

r sin θ φ


∇=
















2

2

2

2

2

2

2

xyz


=×!××=


1


32


5


2


3


25


0

5

0

6

0

π


π


a


aa


r


a


re dr d


p

ra

z

2

0

5

0

5

0

2

0

2

1


32


=



π


ππ

ZZ Z



2

0

cos sinθθθ ddφ


ψ θ


2

2

0

5

22

1


32


p

ra

z

a


= re



π


2

0

cos


r


a


erdr


aa


a


s

ra

1

0

3

0

2
3

0

3

0

4

0

443


2


3


2


==×


!


=



Z



2

2


0

()

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