The Chemistry Maths Book, Second Edition

(Grace) #1

388 Chapter 13Second-order differential equations. Some special functions


so that


Similarly, withn 1 = 1 − 122 in (13.56),


0 Exercise 26


Series expansions for J


l+ 122

(x)and J


−l− 122

(x)are given by equations (13.48) and


(13.49), respectively. Thus


(13.57)


(13.58)


EXAMPLE 13.13Forl 1 = 10 ,


Equations (13.57) and (13.58) show that whereasJ


l+ 122

(x) 1 = 10 at the origin (x 1 = 10 )


and is therefore finite for all values of x,J


−l− 122

(x) 1 → 1 ∞asx 1 → 10.


The functions of half-integral order are the Bessel functions that occur in the


partial wave method in the theory of scattering processes. They occur there in the


forms, forl 1 ≥ 10 ,


(13.59)
jx

x


Jx x


x


J


ll l

l

l

()=,=() () ( )− (


+/

+

−−/

ππ


2


1


2


12

1

12

η xx)


Jx


x


xx


x


x



= −+−










=


12

24

2


1


24


2


()


!!


cos


ππ





Jx x


xx


x


x


x


12

12

24 3

2


1


35


2


3


()


!!!


= −+−










=−


ππ


 ++−










=


x


x


x


5

5


2


!


 sin


π


Jx x


x


l


x


l


l

l

−−

−−

=+








12

12

24

2


1


22 1 2 42 1 2


()


π () ()(· ll−





















Jx x


x


l


x


ll


l

l

+

+

=−










++


12

12

24

2


1


22 3 2 42 3 2


()


π () ()(· 5 5)














Jx


x


JxJx


x


x


x


x


−−

=− − =− +





32 12 12

12


() () ()


cos


sin


π







Jx


x


JxJ x


x


x


x


x


32 12 12

12


() () ()


sin


=−= −cos









π

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