The Chemistry Maths Book, Second Edition

(Grace) #1

14.8 Exercises 415


(i)Show that the equation is separable in spherical polar coordinates, with the same


angular wave functions, the spherical harmonics (14.68), as for the hydrogen atom.


(ii)Show that the radial equation reduces to the Bessel equation (13.60) for spherical


Bessel functionsj


l

(x)where, as in Section 14.5 for the particle in a circular box,


.(iii)Use the boundary condition to find an expression for the quantized


energy in terms of the zeros of the Bessel functions. (iv)Find the wave function and


energy of the ground state.


Section 14.7


16.Find the solution of the wave equation for the vibrating string that satisfies the initial


conditions


y(x, 1 0) 1 = 131 sin 1 πx 2 l,(∂y 2 ∂t)


t= 0

1 = 1 0.


17.A homogeneous thin bar of length land constant cross-section is perfectly insulated


along its length with the ends kept at constant temperatureT 1 = 10 (on some temperature


scale). The temperature profile of the bar is a functionT(x, t)of position x( 01 ≤ 1 x 1 ≤ 1 l) and


of time t, and satisfies the heat-conduction (diffusion) equation where Dis


the thermal diffusivity of the material. The boundary conditions areT(0, 1 t) 1 = 1 T(l, 1 t) 1 = 10.


Find the solution of the equation for initial temperature profileT(x, 1 0) 1 = 131 sin 1 πx 2 l.



  1. (i) Find the general solution of the Laplace equation in the rectangle


01 ≤ 1 x 1 ≤ 1 a, 01 ≤ 1 y 1 ≤ 1 bsubject to the boundary conditions


u(0,y) 1 = 1 0, u(a, y) 1 = 10


u(x, 0) 1 = 1 0, u(x, b) 1 = 1 f(x)


wheref(x)is an arbitrary function of x. (ii)Find the particular solution for


.
fx

x


a


() sin=


3 π










=


2

2

2

2

0


u


x


u


y




=




T


t


D


T


x


2

2

xmEr= 2


2



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