The Chemistry Maths Book, Second Edition

(Grace) #1

466 Chapter 16Vectors


where I 1 = 1 mr


2

is the moment of inertia about the axis of rotation. The relation


between land yis less simple than that given by (16.61) for arbitrary motion of a


particle or for the rotation of a rigid body. The general relation is


l 1 = 1 I


ω
(16.62)

where Iis a quantity with nine components called the moment of inertia tensor (or


matrix), and is discussed in Example 19.15.


0 Exercise 44


Conservation of angular momentum


As discussed in Example 16.9, Newton’s second law of motion can be written as


Taking the cross product of rwith both sides of this equation gives


The left side is the torque Tacting on the system (Example 16.16). The right side is,


using the product rule of differentiation (valid for both scalar and vector products),


But is parallel to p, and their vector product is zero. Therefore, sincer 1 z 1 p 1 = 1 l,


(16.63)


This form of Newton’s second law, that the rate of change of angular momentum of a


system is equal to the applied torque, shows that the angular momentum of a system


is constant in the absence of external torques.


0 Exercises 45– 47


16.7 Scalar and vector fields


A function of the coordinates of a point in space is called a function of position or


field. A scalarfunction of position, a scalar field,


f 1 = 1 f(r) 1 = 1 f(x, y, z) (16.64)


has a value at each pointr 1 = 1 (x, y, z); that is, a scalar (a number) is associated with each


point. Examples of scalar fields have been discussed in Chapter 10. A vectorfunction


of position, a vector field,


v 1 = 1 v(r) 1 = 1 v(x, y, z) (16.65)


T


l


=


d


dt


d


dt


r


=v


r


p


rp


r


11 zzz 11 11 p


d


dt


d


dt


d


dt


=−()


rF r


p


11 zz= 11


d


dt


F


p


t


=


d


d


.

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