The Chemistry Maths Book, Second Edition

(Grace) #1

16.9 Divergence and curl of a vector field 469


(16.71)


is the electrostatic field of charge q


1

, andφ 1 = 1 V 2 q


2

1 = 1 q


1

24 πε


0

ris the corresponding


(scalar) electrostatic potential field.


The meaning of the gradient of a function of positionf(r)is clarified by considering


how the value of the function changes from point to point in space. We consider


a differential (infinitesimal) displacementr 1 → 1 r 1 + 1 dror, in cartesian components,


(x, y, z) 1 → 1 (x 1 + 1 dx, y 1 + 1 dy, z 1 + 1 dz):


dr 1 = 1 (dx, dy, dz) 1 = 1 idx 1 + 1 jdy 1 + 1 kdz (16.72)


The corresponding change in the function,df 1 = 1 f(r 1 + 1 dr) 1 − 1 f(r), is the total differential


(16.73)


This can be written as the scalar product of the gradient∇fand the displacement dr


(Equations (16.68) and (16.72)),


so that


df 1 = 1 ∇f 1
·

1 dr (16.74)


The quantity∇fis therefore the generalization to three dimensions of the ordinary


derivativedf 2 dx; the vector operator ∇is the generalization of the differential


(gradient) operatord 2 dx, and is sometimes written asd 2 dr.


16.9 Divergence and curl of a vector field


The divergence


The divergenceof a vector fieldv(r) is defined as the scalar quantity


(16.75)


In hydrodynamics, the vector field is the velocity field of a fluid, and the divergence is


a flux density; the value of div 1 v(r)dVat a point ris a measure of the net flux, or rate


of flow, of fluid out of a volume elementdVat the point.


divvv==
















∇∇
·

v


v
v

x

y

z

xyz





















 ++ =




f


x


f


y


f


z


dx dy dz


f


ijkijk 11
·

()


xx


dx


f


y


dy


f


z



  • dz










df


f


x


dx


f


y


dy


f


z


= dz
















Er==−∇


q


r


1

0

2

4 πε


ˆ φ

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