The Chemistry Maths Book, Second Edition

(Grace) #1

470 Chapter 16Vectors


We consider here only the special case of a vector field that is the gradient of a scalar


field,v 1 = 1 ∇f. Then


(16.76)


It follows that∇ 1


·


1 ∇ 1 = 1 ∇


2

is the Laplacian operator. When a scalar fieldf(r)satisfies


Laplace’s equation ∇


2

f 1 = 10 at a point then the derived vector field ∇fhas zero


divergence at the point, and there is no net flux out of a volume element at the point.


This is the case for an incompressible fluid in a region containing no sources (of fluid)


or sinks and for an electrostatic field in a region free of charge.


The curl


The curl(or rotationrot 1 v) of a vector fieldv(r) is defined as the vector


(16.77)


(see Equations (16.52) and (16.53)). In hydrodynamics, the curl of the velocity field at


a point is a measure of the circulation of fluid around the point.


A vector field that is the gradient of a scalar field has zero curl,


curl 1 v 1 = 10 if v 1 = 1 grad 1 f (16.78)


Thus, the electrostatic field is the gradient of the scalar electrostatic potential,


E 1 = 1 −∇φ, so that∇ 1 z 1 E 1 = 10. On the other hand, a vector field that is itself the curl of a


vector field has zero divergence,


div 1 v 1 = 1 0ifv 1 = 1 curl w (16.79)


Thus, the magnetic field can always be expressed as the curl of a vector function,


B 1 = 1



1 z 1 A, where Ais called the magnetic vector potential. Then


1
·

1 B 1 = 1 0.


0 Exercises 51–55


=








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∇∇ 11 z


v


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vv

z

y

xz

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i


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y

x


























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v
v

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2

2

2

2

2

2

f


x


f


y


f


z


divv=∇ ∇ =






























+
··

f


xy z


k


f


x


f


y


ij ij


∂∂









f


z


k

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