The Chemistry Maths Book, Second Edition

(Grace) #1

502 Chapter 18Matrices and linear transformations


18.2 Some special matrices


Square matrices


If the number of rows of a matrix is equal to the number of columns,m 1 = 1 n, the matrix


is called a square matrixof ordern. For example, a square matrix of order 3 is


(18.11)


In such a matrix, the diagonal containing the elementsa


11

, a


22

, =,a


nn

is called the


principal diagonal(the word ‘principal’ is often omitted), and the elementsa


ii

on this


diagonal are called the diagonal elementsof the matrix. Those elements,a


ij

fori 1 ≠ 1 j,


not on the diagonal are called the off-diagonal elements; the off-diagonal elements of


the matrix (18.11) area


12

,a


13

,a


23

,a


21

,a


31

,anda


32

.


A matrix whose off-diagonal elements are all zero is called a diagonal matrix; for


example,


(18.12)


The diagonal matrix of order nwhose diagonal elements are all unity is called the unit


matrix I(orI


n

) of order n. For order 3,


(18.13)


Two important scalar properties of a square matrix Aare the determinant of the


matrix, denoted by|A|or det 1 A,


(18.14)
||AA==det

aaa a


aaa a


aaa


n

n

11
12 13

1

21 22 23

2

31 32 3







33

3

1 23




 





a


aaa a


n

n nn nn

I=


















100


010


001


(unit mattrix)


a


a


a


11

22

33

00


00


00




















(diiagonal matrix)


aaa


aaa


aaa


11
12 13

21 22 23

31 32 33




















()square matrix

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