The Chemistry Maths Book, Second Edition

(Grace) #1

510 Chapter 18Matrices and linear transformations


But two matrices need not commute even if they are both square.


EXAMPLE 18.10Non-commuting matrices


If


then


but


so thatAB 1 ≠ 1 BA.


0 Exercise 39


Because of the possibility of non-commutation, it is essential that the correct order of


the factors in a product be observed. In the product AB, the matrix Bis premultiplied,


or multiplied from the left, by A; the matrix Ais postmultiplied, or multiplied from


the right, by B.


A quantity that plays an important role in quantum mechanics is the commutator


of the matrices Aand B,


[A, B] 1 = 1 AB 1 − 1 BA (18.32)


0 Exercises 40, 41


EXAMPLE 18.11The Pauli spin matrices


In quantum mechanics, electron spin is sometimes represented by the three Pauli


spin matrices, one for each cartesian component of the spin angular momentum,


(18.33)
SS S

xy z

i


i


=










,=











,=


1


2


01


10


1


2


0


0


1





22


10


01














BA=


















=










11


10


10


00


10


10


AB=


















=










10


00


11


10


11


00


AB=










,=










10


00


11


10

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