The Chemistry Maths Book, Second Edition

(Grace) #1

18.6 Orthogonal matrices and orthogonal transformations 521


A nonsingular transformation Afollowed by its inverse transformationA


− 1

(orA


− 1

followed by A) is therefore equivalent to the identity transformation I; that is, the


‘transformation’ that leaves every vector unchanged. Thus


if x′ 1 = 1 Ax and x′′ 1 = 1 A


− 1

x′ then x′′ 1 = 1 A


− 1

Ax 1 = 1 x (18.54)


EXAMPLE 18.21The matrix


is nonsingular, with determinant det 1 A 1 = 1 cos


2

1 θ 1 + 1 sin


2

θ 1 = 11 , and represents rotation


through angleθ. The corresponding inverse transformation is the rotation through


angle−θ, with matrix


andB 1 = 1 A


− 1

is the inverse matrix of A. Thus


In this particular case, the inverse is also equal to the transpose,A


− 1

1 = 1 A


T

18.6 Orthogonal matrices and orthogonal transformations


A nonsingular square matrix is called orthogonalwhen its inverse is equal to its


transpose,


A


− 1

1 = 1 A


T

(orthogonal matrix) (18.55)


For example, the matrix discussed in Example 18.21 is orthogonal:


(18.56)


The characteristic property of an orthogonal matrix is that its columns (and its rows)


form a system of orthogonal unit vectors (orthonormal vectors). For order 3, let


Aa==bc(18.57)




















abc


abc


abc


1
11

222

333

())


AA=











,=



cos sin


sin cos


cos sin


sin


θθ


θθ


θθ


T

θθθcos










=



A


1

BA=











cos sin −


sin cos


cos sin


sin co


θθ


θθ


θθ


θ ssθ










=










=


10


01


I


B=


−−−


−−










=


cos( ) sin( )


sin( ) cos( )


θθcos


θθ


θθθ


θθ


sin


−sin cos










A=











cos sin


sin cos


θθ


θθ

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