The Chemistry Maths Book, Second Edition

(Grace) #1

528 Chapter 18Matrices and linear transformations


represented by the number + 1 , clearly satisfies the group multiplication table,


Table 18.1, and is called the trivialor totally symmetricrepresentation of the group.


Every group has such a representation. Table 18.3, obtained from the multiplication


table 18.1 by replacing each operation by its representative± 1 inΓ


2

, shows thatΓ


2

is indeed a representation of the group.


In the same way, replacing each operation in Table 18.1 by its representative matrix


in the two-dimensional representationΓ


3

confirms that these matrices satisfy the


multiplication table.


The matrices of the two-dimensional representation Γ


3

can be derived by


considering the result of applying each symmetry operation to the coordinates of a


point in the plane. Thus, the operation Ais the anticlockwise rotation through


θ 1 = 1 120°about the origin and its representative matrix is


(18.67)


The rotation Bis the inverse of A, sinceAB 1 = 1 BA 1 = 1 E, and its representative matrix B


is the transpose matrix of A(all the matrices are orthogonal, with inverse equal to


transpose). Similarly, the operation C, rotation through 180° about the Ocaxis (the


y-axis), transforms a vectorr 1 = 1 (x, y)into the vectorr′ 1 = 1 (−x, y). Its representative


matrix is therefore


(18.68)


since


(18.69)


It is possible to construct any number of representations of all possible dimensions for


any group, but it can be shown that only a certain number of these (the ‘irreducible



















=











10


01


x


y


x


y


C=











10


01


A=


°− °


°°


=













cos sin


sin cos


120 120


120 120


11


2


3


2


3


2


1


2


















Table 18.3 Multiplication table of


Γ


2



  • 1 + 1 + 1 − 1 − 1 − 1




  • 1 + 1 + 1 + 1 − 1 − 1 − 1




  • 1 + 1 + 1 + 1 − 1 − 1 − 1




  • 1 + 1 + 1 + 1 − 1 − 1 − 1




− 1 − 1 − 1 − 1 + 1 + 1 + 1


− 1 − 1 − 1 − 1 + 1 + 1 + 1


− 1 − 1 − 1 − 1 + 1 + 1 + 1

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