The Chemistry Maths Book, Second Edition

(Grace) #1

19.3 Properties of the eigenvectors 537


(ii) The characteristic equation of the symmetric matrix


with nondegenerate eigenvalueλ


1

1 = 14 and the pair of degenerate valuesλ


2

1 = 1 λ


3

1 = 11.


The secular equations are


Forλ 1 = 14 : The solution isx 1 = 1 y 1 = 1 zand the eigenvector is , c


1

arbitrary.


For λ 1 = 11 : Each secular equation givesx 1 + 1 y 1 + 1 z 1 = 10 , and every independent pair


of vectors that satisfy this condition is a solution for the degenerate eigenvalue;


for example,


and


0 Exercises 10, 11


Two types of matrices whose eigenvalues are of greatest interest in the physical


sciences are real symmetric matrices (symmetric matrices whose elements are all real


numbers) as in Example 19.4(ii), and the complex Hermitian matrices described in


Section 19.6. These matrices have real eigenvalues.


19.3 Properties of the eigenvectors


Property 1.If xis an eigenvector corresponding to eigenvalue λ, then kxis also


an eigenvector corresponding to the same eigenvalue, for any nonzero value of the


number k:


if Ax 1 = 1 λx then A(kx) 1 = 1 k(Ax) 1 = 1 k(λx) 1 = 1 λ(kx) (19.12)


Eigenvectors that differ only in a constant factor are not treated as distinct. It is


convenient and conventional to choose the factor kto make the eigenvector a unit


vector; that is, to normalize the vector.


x


33

1


2


3


=















c
x

22

1


1


2


=















c


x


11

1


1


1


=














c


()


()


()


2


2


2


0


0


0


−+



















+−


=


=


=


λ


λ


λ


x


x


x


y


y


y


z


z


z


211


121


112


211


12 1


112

















is =


λ


λ


λ


(()()41 0


2

−−=λλ

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