The Chemistry Maths Book, Second Edition

(Grace) #1

19.4 Matrix diagonalization 545


EXAMPLE 19.11Diagonalization


The inverse of the matrix Xof the eigenvectors of Ain Example 19.10 is


so that


0 Exercises 25–28


Similarity transformations


Two square matrices Aand Bare called similar matricesor similarity transformsif


they are related by the similarity transformation


2

B 1 = 1 C


− 1

AC (19.29)


where C is a nonsingular matrix. Equation (19.28) is therefore a similarity


transformation that reduces Ato diagonal form. When Ais symmetric then, by theorem


(19.23), the eigenvectors of Aare orthonormal and Xin (19.28) is an orthogonal


matrix, withX


− 1

1 = 1 X


T

. A symmetric matrix is therefore reduced to diagonal form


by the orthogonal transformation


D 1 = 1 X


T

AX (19.30)


Two important invariance propertiesof similarity transforms follow from equations


(18.38) to (18.40) for the determinant and trace of a matrix product: ifB 1 = 1 C


− 1

AC


then


det 1 B 1 = 1 det 1 A invariance of the determinant (19.31)


tr 1 B 1 = 1 tr 1 A invariance of the trace (19.32)


For example,


det 1 B 1 = 1 det 1 (C


− 1

AC) 1 = 1 det 1 (ACC


− 1

) 1 = 1 det 1 (AI) 1 = 1 det 1 A


XAX



=



−−


















1

10 1


411


311


211


11 4 5


1100


011


123


111


100


01



























=



00


002














=D


X



=



−−















1

10 1


411


311


2

In his 1878 monograph on the theory of matrices, Frobenius defined similar matrices, discussed the


properties of orthogonal matrices and transformations, and showed the relationship between the algebras of matrices


and quaternions by determining four 2 1 × 1 2 matrices whose algebra is that of the quaternion quantities 1, i,j,k.

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