The Chemistry Maths Book, Second Edition

(Grace) #1

19.6 Complex matrices 553


The inner product is complex in general, but the quantity


(19.55)


is a positive real number, and defines the length, or norm, of the vector,


EXAMPLE 19.17For the vectorsa 1 = 1 (1 1 + 1 i, 3, 2i)andb 1 = 1 (2 1 − 1 i, 4i, −1),


0 Exercise 39


A vector divided by its norm is a unit vector, and two vectors are orthogonal when


their inner product is zero. The complex analogue of an orthonormal system of


vectors is then


(19.56)


Such a system of vectors is called unitary.


Hermitian matrices


A complex square matrix that is equal to its Hermitian conjugate is called a Hermitian


matrix,


A



1 = 1 A (Hermitian matrix) (19.57)


A real Hermitian matrix is a symmetric matrix.


aa


kl

kl


kl



=


=








1


0


if


if


ab



=− − ()( )
()















132 =− −


2


4


1


ii 12


i


iii+++−−=+ 34 ii2 1 1 11()( )()i


bb



=+ − − ()(
()















241 =+ −


2


4


1


ii 22


i


iii))( )()+−44 1516122ii+ = + + =


aa



=− − ()()
()

















132 =− ++


1


3


2


ii 11


i


i


ii 332229415


2

+−()()ii=++=


||a = aa



.


=++aaa


1

2

2

2

3

2

aa
·

==




















aa



()aaa


a


a


a


123

1

2

3

*** ==++aa aa aa


11 22 33


Free download pdf