The Chemistry Maths Book, Second Edition

(Grace) #1

554 Chapter 19The matrix eigenvalue problem


EXAMPLE 19.18Show that the following matrix is Hermitian:


We have


0 Exercise 40


Unitary matrices


A complex square matrixUis called unitary when its Hermitian conjugate is equal to


its inverse,


U



1 = 1 U


− 1

(19.58)


The characteristic property of a unitary matrix is that its columns (and its rows)


form a unitary system of orthonormal vectors as defined by (19.56) (compare the


discussion of orthogonal matrices in Section 18.6). For order 3, let


(19.59)


wherea



a 1 = 1 b



b 1 = 1 c



c 1 = 11 anda



b 1 = 1 b



c 1 = 1 c



a 1 = 10. The Hermitian conjugate of Uis


(19.60)


and


(19.61)


0 Exercises 41, 42


UU


a


b


c


abc


aa ab ac






†††

==()




















bba bb bc


ca cb cc


†††

†††













=




100


010


001














=I


U


a


b


c








==**




















aaa


bb


123

12

bb


ccc


3

123





















Uabc==



















()


abc


abc


abc


1 11

222

333



AA(A)



=















,==









323


23 1


323


23 1


i


i


i


i


T









=A


A=















323


23 1


i


i

Free download pdf