The Chemistry Maths Book, Second Edition

(Grace) #1

21.12 Exercises 625


6.For the data in Exercise 1,(i) calculate and , (ii)use equations (21.7) and


(21.9) to compute the standard deviation and the skewness.


Section 21.4


7.A set of 10 balls consists of 6 red balls, 3 blue, and 1 yellow. If a ball is drawn at random,


find the probability that it is (i)red, (ii)yellow,(iii)red or yellow,(iv)not blue,(v)not


yellow.


8.A set of 50 numbered discs consists of 8 ones, 12 twos, 14 threes, 7 fours, and 9 fives.


If one disc is drawn at random, what is the probability that its number is (i)2, (ii)4,


(iii)2 or 4, (iv)≤ 1 4, (v)odd.


9.Find the probabilitiesP(2) toP(12) of all the possible outcomes of two throws of a die.


10.Find the probability of the following total scores from three throws of a die: (i)4, (ii)8,


(iii)4 or 8, (iv)more than 15.


11.A particle can be in three states with energiesε


0


1

, andε


2


0

1 < 1 ε


1

1 < 1 ε


2

), and probability


distribution at temperatureT. The quantity qis called the particle


partition function.


(i) Express qin terms of Tand the energies (use∑


i

P


i

1 = 11 ). (ii) Find the probability


distribution in the limit (a)T 1 → 10 , (b)T 1 → 1 ∞. (iii)Find the (combined) probability


distribution for a system of three independent particles.


Section 21.5


12.Find the probability that at least 3 heads are obtained from 5 tosses of (i)an unbiased


coin, (ii)a coin with probability 0.6 of coming up tails.


13.A system that can exist in a number of states with energiesE


0

1 < 1 E


1

1 < 1 E


2

1 <1-has


probability 0.1 of being in an excited state (withE 1 > 1 E


0

). Find the probability that in 10


independent observations, the system is found in the ground state (withE 1 = 1 E


0

) (i)every


time, (ii)only 5 times, (iii)at least 8 times.


14.Use the probability distribution of the outcomes of throwing a pair of dice, from


Exercise 9, to calculate the probability that two throws of a pair of dice have outcome


(i) 81 + 112 (one eight and one twelve), (ii) 91 + 111 , (iii) 101 + 110. Hence (iv)find the


probability of outcome 20 from two throws of two dice.


15.Use the probability distribution of the outcomes of throwing a pair of dice, from Exercise 9,


to calculate the probability that three throws of two dice have total outcome 30.


Section 21.6


16.List the permutations of 4 different objects.


17.List the permutations of 5 different objects taken 2 at a time.


18.List the combinations of 5 different objects taken 2 at a time.


19.List the distinct permutations of the 5 objects, A, A, A, B, and B.


20.What is the number of distinct permutations of 8 objects made up of 4 of type A, 3 of B,


and 1 of C?


21.Given an inexhaustible supply of objects A, B, and C, what is the number of distinct


permutations of these taken 8 at a time?



  1. (i) Given 3 distinguishable particles each of which can be in any of 4 states with


(different) energies E


1

, E


2

, E


3

, and E


4

, (a)what is the total number of ways of distributing


the particles amongst the states?, (b)how many states of the system have total energy


E


1

1 + 1 E


2

1 + 1 E


4

? (ii) Repeat (i)for 3 electrons instead of distinguishable particles.


Pe q


i

kT

i

=



ε

x


3

xx,


2

,

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