The Chemistry Maths Book, Second Edition

(Grace) #1

76 Chapter 3Transcendental functions


EXAMPLE 3.14Express and in terms ofsin 1 θandcos 1 θ.


From equations (3.21),


Figure 3.11 shows that and (see also Example 3.5). Therefore


Similarly, using equations (3.22),


0 Exercises 24


The expressions for the sum and difference of angles are important for the calculation


of integrals (see Chapter 6) and for the description of the combination (interference)


of waves.


EXAMPLE 3.15The harmonic wave travelling in the x-direction described in


Example 3.7 and shown in Figure 3.12 has wave function


The same wave travelling in the opposite direction is (replacing tby −t)


As the waves overlap they interfere to give a new wave whose wave function is a linear


combination of the form


ψ 1 = 1 aφ


+

1 + 1 bφ



=−







++







aA 


x


tbA


x


sin 22 ππsin t


λ


ν


λ


ν


φ


λ


ν



=+








A


x


sin2π t


φ


λ


ν


+

=−








A


x


sin2π t


cos cos cos sin sin sin


πππ


222


±







θθθθ==∓∓


sin cos


π


2


±








θθ=


cos


π


2


sin = 0


π


2


= 1


sin sin cos cos sin


ππ π


22 2


±







θθθ=±


cos


π


2


±








θ
sin

π


2


±








θ

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